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Organic bismuth compound, method for producing same, living radical polymerization initiator, method for producing polymer using same, and polymer

外国特許コード F110004863
整理番号 K05610WO
掲載日 2011年7月22日
出願国 大韓民国
出願番号 20077015664
公報番号 20070086991
公報番号 100885109
出願日 平成19年7月9日(2007.7.9)
公報発行日 平成19年8月27日(2007.8.27)
公報発行日 平成21年2月20日(2009.2.20)
国際出願番号 JP2005023093
国際公開番号 WO2006062255
国際出願日 平成19年7月9日(2007.7.9)
国際公開日 平成18年6月15日(2006.6.15)
優先権データ
  • 特願2004-358238 (2004.12.10) JP
  • 特願2005-255327 (2005.9.2) JP
発明の名称 (英語) Organic bismuth compound, method for producing same, living radical polymerization initiator, method for producing polymer using same, and polymer
発明の概要(英語) Disclosed is an organic bismuth compound represented by the following formula (1). (1) (In the formula, R1 and R2 respectively represent a C1-C8 alkyl group, an aryl group, a substituted aryl group or an aromatic heterocyclic group; R 3 and R4 respectively represent a hydrogen atom or a C1-C8 alkyl group; and R5 represents an aryl group, a substituted aryl group, an aromatic heterocyclic group, an acyl group, an amide group, an oxycarbonyl group or a cyano group.)
特許請求の範囲(英語) [claim1]

(1)

(The cursor and, indicating to the alkyl group on the Ci cs, ariiru, ariiru substituents or aromatic terrorist ring based. R3 and R4 is hydrogen atoms or (^ ~ (: archi Le base8 to show. R5 indicating the terror ring based, Ashiru, amide, okishi force Le ponil or shiano based ariiru based ariiru substituents, aromatic. )
[claim2]
2. method of manufacture of organic bismuth compounds represented by the expression that characterized the reaction compounds of formula (3) and (4) or expression (5) of the compound (1).


[The! ^ E & ^ up, same as above. Show Atom or alkali metal. 〕


[The R3and R4 and R-5 , same as above. X shows the halogen atom. 〕


(5)

[The R3and R4 and R-5 , same as above. 〕
[claim3]
3. that is represented by the equation (2) living radical polymerization initiator


(The 1 & 1 is 2 . ( 1~ (: indicates the terrorist ring based to8 arukiru, ariiru, ariiru substituents or aromatic. 3 and 1 4 hydrogen atoms or (^ ~ (: archi Le base8 to show. R5 indicating the terror ring based, Ashiru, amide, okishikaruboniru or shiano based ariiru based ariiru substituents, aromatic. )

4 fabrication of features to the polymerization of vinyl Mon Mar by using living radical polymerization initiator that is represented by the equation (2), living radical polymer.
[claim4]
5. living radical polymerization initiator and is represented by the equation (2) polymerization monomer using azo initiator to feature living radical polymer manufacturing method.
[claim5]
6. can be obtained by polymerization of vinyl Mon Mar using living radical polymerization initiator that is represented by the equation (2), living radical polymer.
[claim6]
7. can be obtained by polymerization of vinyl monomer azo initiator using the living radical polymerization initiator and is represented by the equation (2), living radical polymer.
[claim7]
8. a mixture of living radical polymerization initiator that is represented by the equation (2) and aゾ of polymerization initiator.
[claim8]
9. random copolymers to polymerization of bielmonoma one of the two or more living radical polymerization initiator that is represented by the equation (2) by using the feature to production methods.
[claim9]
10. random copolymers to and living radical polymerization initiator that is represented by the equation (2) polymerization of two or more monomer azo initiator using the manufacturing method.

1 1. And can be obtained by polymerization of vinyl monomer between more than two living radical polymerization initiator that is represented by the equation (2) by using the random copolymer. :

1 2. Can be obtained by polymerization of two or more Bell monomer using living radical polymerization initiator that is represented by the equation (2) and azo initiator, a random copolymer.

1 3. Macrolibinglazcal polymerization initiator, can be obtained by polymerization of vinyl Mon 5 Mar using living radical polymerization initiator that is represented by the equation (2).

1 4. By polymerization of vinyl monomers, using living radical polymerization initiator that is represented by the equation (2) and azo initiator f decubitus and macrolibinglazcal polymerization initiator can be.

1 5. Request scope 1 paragraph 3 to macrolibinglazcal initiator in using vinyl 10 block copolymers to Nile monomer polymerization production methods.

1 6. Request scope 1 paragraph 4 on macrolibinglazcal initiator in using PVC ♦ of block copolymers to Nile monomer polymerization production methods.

1 7. And can be obtained by polymerization of PVC nylmonomer by macrolibinglazcal started in request scope 1 paragraph 3 to block copolymers.

15 1 8. Can be obtained, and polymerization of PVC nylmonomer by macrolibinglazcal started in request scope 1 paragraph 4 to block copolymers.

1 9. Living radical polymerization initiator that is represented by the equation (2) and the JI telling compounds, gistibine compounds and dipisumutin: drinking water characteristics to the polymerization of vinyl monomer, using a mixture of compounds chosen ί 匕 compounds from at least one 0 glazkarpolmer manufacturing methods. '

2 0. Living radical polymerization initiator that is represented by the equation (2), azo initiator, and the JI telling compounds, gistibine compounds and compound gibismuthin voted in characteristics to the polymerization of vinyl monomer using a mixture of at least one compound, living radical polymer manufacturing methods.

5 2 1. And can be obtained by polymerization of vinyl monomers, using a mixture of compounds of living radical polymerization initiator that is represented by the equation (2), JI telling compounds, gistibine compounds and gibismuthin compounds and elected at least one living Radi CAL polymer. '

2 2. Living radical polymerization initiator that is represented by the equation (2), azo initiator, and the JI telling compounds, gistibine compounds and compound gibismuthin voted in by polymerization of vinyl monomer using a mixture of at least one compound, obtained
2 3. Living radical polymerization initiator that is represented by the equation (2), JI telling compounds, gistibine compounds and gibismuthin compounds and elected at least one compound mixture.

2 4. Living radical polymerization initiator that is represented by the equation (2), azo initiator and 0 and the JI telling compounds, gistibine compounds and compound gibismuthin voted is a mixture of at least one compound.

2 5. Random copolymer 5 to 2 or more monomer polymerization using a mixture of living radical polymerization initiator that is represented by the equation (2), JI telling compounds, gistibine compounds and gibismuthin compounds and elected at least one compound, manufacturing methods.

2 6. Living radical polymerization initiator that is represented by the equation (2), azo initiator, and the JI telling compounds, gistibine compounds and gibismuthin compounds chosen is random copolymers to feature heavily if two or more monomer using a mixture of at least one compound, manufacturing methods.

0 2 7. And can be obtained by polymerization of two or more Bell monomer using a mixture of compounds chosen living radical polymerization initiator that is represented by the equation (2), and JI telling compound discipine compounds and gibismuthin compounds from at least one of the random copolymer.

' 2 8. Living radical polymerization initiator that is represented by the equation (2), azo initiator, 5 and the JI telling compounds, gistibine compounds and gibismuthin compounds chosen is random copolymers using a mixture of at least one compound, two or more monomer heavy and can be obtained.
[claim10]
29. living radical polymerization initiator that is represented by the equation (2) and Sitel ', may be obtained by polymerization of vinyl monomers, using a mixture of compounds selected from the Lido compounds, gistibine compounds and compound gibismuthin at least one macro living glazcal polymerization initiator.
[claim11]
30. living radical polymerization initiator that is represented by the equation (2), azo initiator, and the JI telling compounds, gistibine compounds and gibismuthin compounds voted in by polymerization of vinyl monomer using a mixture of at least one compound, obtained and macrolibinglazcal polymerization initiator can be.
[claim12]
31. scope of claims paragraph 29 listed in... of block copolymers vinyl Nile monomer polymerization by macrolibinglazcal start to production methods.
[claim13]
32. method of manufacture of block copolymers vinyl Nile monomer polymerization by macrolibinglazcal initiator listed in request scope paragraph 30 to feature.
[claim14]
33. can be obtained by polymerization of vinyl nylmonomer by macrolibinglazcal initiator listed in request scope paragraph 29, block copolymers.
[claim15]
34. can be obtained by polymerization of vinyl nylmonoma a request scope paragraph 30 mentioned macrolibinglazcal initiator using the block copolymer.
[claim16]
35. that is represented by the formula (a) (2) living radical polymerization initiator,

the mixture of living radical polymerization initiator that is represented by the formula (b) (2) and aゾ of polymerization initiator,

mixture of living radical polymerization initiator that is represented by the formula (c) (2) and JI telling compounds chosen ones, compounds gistibine and gibismuthin compounds from at least one compound, or

living radical polymerization initiator that is represented by the equation (d) (2), azo initiator you. and, drawn from JI telling compounds, gistibine compounds and compound gibismuthin mixture of compounds that at least one species, these (a)-(d) manufacturing method of dissecting acid containing resin polymerization the monomer by using one to feature. 36. in request scope paragraph 35 can be obtained by the method of acid dissociation of containing resin.
[claim17]
37. and with sense of radiation resin composition comprising a dissociation of acid-containing resin and sense of radiation-acid generators wherein acid dissociation of containing resin,

living radical polymerization initiator, is represented by the formula (a) (2)

the mixture of living radical polymerization initiator that is represented by the formula (b) (2) and azo initiator,

mixture of living radical polymerization initiator that is represented by the formula (c) (2) and JI telling compounds chosen ones, compounds gistibine and gibismuthin compounds from at least one compound, or

living radical polymerization initiator that is represented by the equation (d) (2), azo initiator you. and, drawn from JI telling compounds, gistibine compounds and compound gibismuthin mixture of compounds that at least one species, these (a)-... (d) the sense of radiation curable compounds that characterized by resins by polymerization of vinyl monomer using either.
  • 出願人(英語)
  • OTSUKA CHEMICAL
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • 発明者(英語)
  • YAMAGO SHIGERU
  • KAMESHIMA TAKASHI
  • KAWANO KAZUHIRO
  • ITO OSAMU
  • DAIMON EMIKO
  • SHU KEN
  • SUGOH KUNIHIKO
国際特許分類(IPC)
参考情報 (研究プロジェクト等) PRESTO Synthesis and Control AREA
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