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Organic antimony compound, process for producing the same, living radical polymerization initiator, process for producing polymer using the same, and polymer

外国特許コード F110004963
整理番号 K05609WO
掲載日 2011年7月28日
出願国 大韓民国
出願番号 20077001062
公報番号 20070019027
公報番号 100852030
出願日 平成19年1月16日(2007.1.16)
公報発行日 平成19年2月14日(2007.2.14)
公報発行日 平成20年8月13日(2008.8.13)
国際出願番号 JP2005012016
国際公開番号 WO2006001496
国際出願日 平成19年1月16日(2007.1.16)
国際公開日 平成18年1月5日(2006.1.5)
発明の名称 (英語) Organic antimony compound, process for producing the same, living radical polymerization initiator, process for producing polymer using the same, and polymer
発明の概要(英語) An organic antimony compound represented by formula (1) wherein R1 and R2 represent a C1- C8 alkyl group, an aryl group, a substituted aryl group, or an aromatic heterocyclic group.
R3 and R4 represent a hydrogen atom or a C1-C8 alkyl group; and R5 represents an aryl group, a substituted aryl group, an aromatic heterocyclic group, an oxycarbonyl group, or a cyano group.
A process for producing a polymer using this organic antimony compound, and a polymer are also provided.
© KIPO & WIPO 2007
特許請求の範囲(英語) [claim1]
1. the organic antimony compound c is represented by expression (1)


(Wherein R1 and R2 are C ^ indicates to the alkyl group of the Cs, ariiru, ariiru substituents or aromatic terrorist ring based. R3 and R4 is hydrogen atoms or (^ ~ (: archi Le base8 to show. R5 indicating the terror ring based, okishi force Le ponil or shiano ariiru base, substituents ariiru and aromatic. )
[claim2]
2. compounds of formula (3) and (4) or expression (5) of the compound reacted to organic antimony compounds represented by the characteristics and expressions (1) manufacturing method.


[Wherein R1 and R2 are same as above. Z indicating the halogen atoms or alkali metal. 〕


[The R3and R4 and R-5 , same as above. X shows the halogen atom. 〕


R3and R4 and R-5 , same as above. 〕
[claim3]
3. in equation (2) table; ' polymerization initiators.


(Wherein R1 and R2 are ^ ~ (^ of indicating to the alkyl group, ariiru, replace it, reel or aromatic terrorist ring based. R3 and R4 is hydrogen atoms or Ci : show for archi Le8 . R6 , ariiru, ariiru substituted aromatic hete ' indicating the mouth rim, Ashiru, okishikaruboniru or shiano based. )

4 fabrication of features to the polymerization of vinyl monomers using living radical polymerization initiator that is represented by the equation (2), living radical polymer.
[claim4]
5. making and living radical polymerization initiator that is represented by the equation (2) polymerization monomer using azo initiator to feature living radical pol Ma.
[claim5]
6. can be obtained, by the Biel monomer polymerization using living radical polymerization initiator that is represented by the equation (2), living radical polymer.
[claim6]
7. can be obtained by polymerization of vinyl monomer azo initiator using the living radical polymerization initiator and is represented by the equation (2), living radical polymer.
[claim7]
8. a mixture of living radical polymerization initiator that is represented by the equation (2) and azo initiator.
[claim8]
9. random copolymers and characteristic to the polymerization of two or more monomer using living radical polymerization initiator that is represented by the equation (2), manufacturing methods.
[claim9]
10. method of manufacture of random copolymer to polymerization of vinyl monomer of two or more azo initiator using the living radical polymerization open agent and is represented by the equation (2) to features.
[claim10]
11. and can be obtained by polymerization of two or more pinilmonomer living radical polymerization initiator that is represented by the equation (2) by using the random copolymer.
[claim11]
12. can be obtained by polymerization of vinyl monomer in the more than two azo initiator using the living radical polymerization initiator and is represented by the equation (2), random copolymer.
[claim12]
13. can be obtained by the Bini Le monomer polymerization using living radical polymerization initiator that is represented by the equation (2), macrolibinglazcal polymerization initiator.
[claim13]
14. can be obtained by polymerization of vinyl monomer azo initiator using the living radical polymerization initiator and is represented by the equation (2), mcclory, Bing radical polymerization initiators.
[claim14]
15. in request scope paragraph 13 mentioned macrolibinglazcal initiator for and block copolymers vinyl monomer polymerization to production methods.
[claim15]
16. in request scope (14) macrolibinglazcal initiator listed for and method of block copolymers to polymerization of vinyl monomer a to feature.
[claim16]
17. in request scope paragraph 13 macrolibinglazcal initiator listed for and block copolymers, may be obtained by polymerization of vinyl monomer 1.
[claim17]
18. in request scope (14) macrolibinglazcal initiator listed for and block copolymers can be obtained by polymerization of pinilmonomer,.
[claim18]
19. bielmosomer polymerization using a mixture of at least one compound at least, be drawn from living radical polymerization initiator that is represented by the equation (2), and Sitel Lido compound discipine compounds and gibismuthin compounds to feature living radical polymer manufacturing method.
[claim19]
20. living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and gibismuthin compounds or from heavy vinyl monomer one using a mixture of elected at least one compound, selective characteristics to living radical polymer manufacturing methods.
[claim20]
21. drawn from living radical polymerization initiator that is represented by the equation (2) and the zither Lido compounds, gistibine compounds and gibismuthin compounds and can be obtained by polymerization of vinyl monomer mixture of compounds of at least one species using less, living glazkarpolmer.

2 2. Living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and gibismuthin compounds or from through Bell monomer polymerization using a mixture of elected at least one compound, shall be obtained living radical polymer.

2 3. Drawn from living radical polymerization initiator that is represented by the equation (2) and the zither Lido compounds, gistibine compounds and gibismuthin compounds at a mixture of at least one compound.

2 4. Living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and gibismuthin compounds or from a mixture of compounds chosen at least one.

2 5. Making random copolymers to feature two or more monomer polymerization using a mixture of at least one compound at least, be drawn from living radical polymerization initiator that is represented by the equation (2) and the zither Lido compounds, gistibine compounds and gibismuthin compounds.

2 6. Living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and gibismuthin compounds or from random copolymer to feature more than two kinds of vinyl monomer polymerization using a mixture of elected at least one compound, manufacturing methods.

2 7. Drawn from living radical polymerization initiator that is represented by the equation (2) and the zither Lido compounds, gistibine compounds and gibismuthin compounds can be obtained by polymerization of two or more pinilmonomer less by using a mixture of at least one compound, a random copolymer.

2 8. Living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and gibismuthin compounds or from random copolymer may be obtained, using a mixture of elected at least one compound, and polymerization of vinyl monomer of two or more.

2 9. Drawn from living radical polymerization initiator that is represented by the equation (2) and the zither Lido compounds, gistibine compounds and dipisumutin compounds can be obtained by polymerization of vinyl monomer using a mixture of at least one compound at the macro living radical polymerization initiators.
[claim21]
30. living radical polymerization initiator that is represented by the equation (2), azo initiator and JI telling compounds, gistibine compounds and compound gibismuthin or et and polymerization of pinilmonomer using a mixture of elected at least one compound, taking macrolibinglazcal polymerization initiator can be obtained.
[claim22]
31. in request scope paragraph 29 listed macrolibinglazcal initiator for and block copolymers vinyl monomer polymerization to feature the production process.
[claim23]
32. in request scope paragraph 30 mentioned macrolibinglazcal initiator for and block copolymers vinyl monomer polymerization to production methods.
[claim24]
33. in request scope paragraph 29 listed macrolibinglazcal initiator for and block copolymers can be obtained by polymerization of vinyl monomer,.
[claim25]
34. in request scope paragraph 30 mentioned macrolibinglazcal initiator for and block copolymers can be obtained by polymerization of vinyl monomer,.
[claim26]
35. that is represented by the formula (a) (2) living radical polymerization initiator,

the mixture of living radical polymerization initiator that is represented by the formula (b) (2) and aゾ of polymerization initiator,

mixture of living radical polymerization initiator that is represented by the formula (c) (2) and JI telling compounds chosen ones, compounds gistibine and gibismuthin compounds from at least one compound, or

living radical polymerization initiator that is represented by the equation (d) (2), azo initiator you. and, drawn from JI telling compounds, gistibine compounds and compound gibismuthin mixture of compounds that at least one species, these (a)-(d) manufacturing method of dissecting acid containing resin polymerization the monomer by using one to feature.
[claim27]
36. in request scope paragraph 35 can be obtained by the method of acid dissociation of based included with resin.
[claim28]
37. sense of emission line of resin composition comprising a dissociation of acid-containing resin and sense of radiation-acid generators in case the said acid dissociation of containing resin,

living radical polymerization initiator, is represented by the formula (a) (2)

the mixture of living radical polymerization initiator that is represented by the formula (b) (2) and azo initiator,

mixture of living radical polymerization initiator that is represented by the formula (c) (2) and JI telling compounds chosen ones, compounds gistibine and gibismuthin compounds from at least one compound, or

living radical polymerization initiator that is represented by the equation (d) (2), azo initiator and I shall, drawn from JI telling compounds, gistibine compounds and compound gibismuthin mixture of compounds that at least one species, these (a)-(d) sense of radiation curable compounds that characterized by resins by polymerization of vinyl monomer by using one.
  • 出願人(英語)
  • OTSUKA CHEMICAL
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • 発明者(英語)
  • YAMAGO SHIGERU
  • RAY BISWAJIT
  • KAMESHIMA TAKASHI
  • KAWANO KAZUHIRO
国際特許分類(IPC)
参考情報 (研究プロジェクト等) PRESTO Synthesis and Control AREA
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