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POLYMER COMPLEX AND PRODUCTION PROCESS THEREFOR

外国特許コード F160008880
整理番号 (S2015-0707-N0)
掲載日 2016年10月25日
出願国 世界知的所有権機関(WIPO)
国際出願番号 2016JP055906
国際公開番号 WO 2016143561
国際出願日 平成28年2月26日(2016.2.26)
国際公開日 平成28年9月15日(2016.9.15)
優先権データ
  • 特願2015-045416 (2015.3.9) JP
発明の名称 (英語) POLYMER COMPLEX AND PRODUCTION PROCESS THEREFOR
発明の概要(英語) The present invention provides a new organic ligand capable of providing a complex that has a three-dimensional network structure due to rare-earth element ions. Also provided is a new polymer complex which includes this organic ligand, has a new function, and contains rare-earth element ions. Furthermore provided are a process for producing the polymer complex and a use of the polymer complex. The present invention relates to a polymer complex having repeating units represented by general formula (10). Ar11 , Ar12 , and Ar13 each represent an aryl group, a heteroaryl group, or an aralkyl group. M1 is a rare-earth element ion. LG is a multidentate ligand which has coordinated to the rare-earth element ion represented by M1 . Ar11 and/or Ar13 can have at least one carboxyl group, the moieties having structures respectively represented by general formulae (11) and (12). -Ar11 -COO- ··· M1 (LG)n1 ·· (11) and -Ar13 -COO- ··· M1 (LG)n3 ·· (12)
特許請求の範囲(英語) [claim1]
1. The below-mentioned general formula (10) with the high-molecular complex which possesses the repetition unit which is shown.
General system (10) in,
Ar (11), Ar (12) and Ar (13), in independence, substitution or non substitution aryl basis, showing substitution or non substitution hetero aryl basis, or substitution or non substitution aralkyl basis,
M (1) is the rare earth element ion,
LG the description above M is the multi seat ligands which coordination are done in the rare earth element ion which is shown with (1), m and n2 is optional integer,
M (1) (LG) [m] with the terminal side which is shown, it connects the phosphine oxide basis in the other repetition unit,
Ar (11) and Ar (13) one side or both are non substitution, or or each one it possesses the carboxyl group 1 at least, the below-mentioned general formula (11) and (12) with it possesses the structure which is shown, n1 and n3 are optional integer,
General system (10) M (1) (LG) in [m]... O=P..., M to show the connection between (1) and O=P, - COO (-)... M (1) (LG) [n2]..., - COO (-) with showing the connection between M (1),
General system (10) the - (12) M (1) (LG) in [n1] the - [3] with the terminal side which is shown, connection with the carboxyl group in the other repetition unit is shown.
[claim2]
2. Ar (11) and Ar (13) both, in the claim 1 which is non substitution the complex of statement.
[claim3]
3. Ar (11) and Ar (13) both, have the carboxyl group 1 respectively, in claim 1 the complex of statement.
[claim4]
4. Either of the claim 1-3 where multi seat ligands LG are [jiketo] chemical compound in 1 sections the complex of statement.
[claim5]
5. [jiketo] chemical compound is shown with general system (3) is the chemical compound which, in claim 4 the complex of statement.
In formula, as for A in independence, the hydrogen atom, the alkyl group or the halogen atom of the carbon count 1-6, as for Z the hydrogen atom or the deuterium atom is shown.
[claim6]
6. [jiketo] chemical compound, acetyl acetone (acac), 2,2,6,6 - tetramethyl heptane - 3,5 - the dione (TMHD), 1,1,1 - [torihuruoroasechiruaseton] (TFA), 1,1,1,5,5,5 - hexa- fluoro acetyl acetone (HFA), and 1- (2 - naphthyl) - 4,4,4 - [torihuruoro] - 1,3 - at least is the chemical compound of 1 where it is chosen from the group which consists of the butanedione kinds, in claim 4 or 5 the high-molecular complex of statement.
[claim7]
7. M (1) at least is the rare earth element ion of 2 types, either of the claim 1-6 in 1 sections the high-molecular complex of statement.
[claim8]
8. Is shown with the below-mentioned general formula (1) it consists of the phosphine oxide compound which, the ligand for the high-molecular rare earth complex.
General system (1) in,
Ar (11), Ar (12) and Ar (13), in independence, substitution or the non substitution aryl basis, substitution or the non substitution hetero aryl basis, or substitution or the non substitution aralkyl basis are shown, Ar (11), Ar (12) and Ar (13) 1 each one have the carboxyl group 1 at least at least.
[claim9]
9. In the claim 8 which Ar (11), Ar (12) and Ar (13), in independence, shows substitution or the non substitution aryl basis, Ar (11), Ar (12) and Ar (13) at least 1 respectively possesses the carboxyl group 1 the ligand of statement.
[claim10]
10. In the claim 8 which Ar (11), Ar (12) and Ar (13), in independence, shows phenyl group, Ar (11), Ar (12) and Ar (13) at least 1 respectively possesses the carboxyl group 1 the ligand of statement.
[claim11]
11. Either of the claim 8-10 in 1 sections general system of statement chemical compound and the rare earth compound which are shown with (1) (however, as for the ion of the rare earth which is included in the rare earth compound M (1) is), and reacting multi seat ligands LG, either of the claim 1-6 in 1 sections general system of statement (10) with production method of the high-molecular complex which includes the process which manufactures the high-molecular complex which possesses the repetition unit which is shown.
  • 出願人(英語)
  • ※2012年7月以前掲載分については米国以外のすべての指定国
  • HOKKAIDO UNIVERSITY
  • 発明者(英語)
  • HASEGAWA YASUCHIKA
  • NAKAJIMA AYAKO
  • NAKANISHI TAKAYUKI
  • KITAGAWA YUICHI
  • FUSHIMI KOJI
国際特許分類(IPC)
指定国 National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
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