TOP > 外国特許検索 > TRIPTYCENE DERIVATIVE USEFUL AS MATERIAL FOR FORMING SELF-ASSEMBLED FILM, METHOD FOR MANUFACTURING SAID TRIPTYCENE DERIVATIVE, FILM USING SAME, METHOD FOR MANUFACTURING SAID FILM, AND ELECTRONIC DEVICE USING SAID METHOD

TRIPTYCENE DERIVATIVE USEFUL AS MATERIAL FOR FORMING SELF-ASSEMBLED FILM, METHOD FOR MANUFACTURING SAID TRIPTYCENE DERIVATIVE, FILM USING SAME, METHOD FOR MANUFACTURING SAID FILM, AND ELECTRONIC DEVICE USING SAID METHOD NEW

外国特許コード F170008961
整理番号 E114P20WO
掲載日 2017年3月9日
出願国 世界知的所有権機関(WIPO)
国際出願番号 2015JP070220
国際公開番号 WO 2016010061
国際出願日 平成27年7月15日(2015.7.15)
国際公開日 平成28年1月21日(2016.1.21)
優先権データ
  • 特願2014-145269 (2014.7.15) JP
発明の名称 (英語) TRIPTYCENE DERIVATIVE USEFUL AS MATERIAL FOR FORMING SELF-ASSEMBLED FILM, METHOD FOR MANUFACTURING SAID TRIPTYCENE DERIVATIVE, FILM USING SAME, METHOD FOR MANUFACTURING SAID FILM, AND ELECTRONIC DEVICE USING SAID METHOD NEW
発明の概要(英語) The present invention pertains to: a Janus-type triptycene derivative which is capable of forming a self-assembled film which does not depend on the material quality of a substrate; a self-assembled film using said Janus-type triptycene derivative; a structure having said film on a surface thereof; a method for manufacturing said film; and an electronic device using said method.
特許請求の範囲(英語) [claim1]
1. The next general formula [I]
(In formula, R (1) saturation of 60 or displays the hydrocarbon radical of unsaturated 2 value from carbon count 2, the particular hydrocarbon radical may possess or more the substituent of one or two, in addition, one in the particular hydrocarbon radical or the carbon atom of two or more the oxygen atom, the sulfur atom and the silicon atom, or - NR (5)- (here, R as for (5), the hydrogen atom, displays the alkyl group of the carbon count 1-10, or the aryl basis of the carbon count 6-30.)So it is possible to be substituted;
As for R (2), from hydrogen atom, or carbon count 1 saturation of 4 or displaying unsaturated hydrocarbon radical;
As for R (3), basis - from R (1)-Z, hydrogen atom, or carbon count 1 saturation of 4 or displaying unsaturated hydrocarbon radical;
Three R as for (4), equality or even when becoming independent be possible to differ respectively, the hydrogen atom and the halogen atom, hydroxyl group, the nitro group and the cyano basis, the amino group, the mono alkyl substitution amino group and the [jiarukiru] substitution amino group, the alkyl group of the carbon count 1-10 which is possible to possess the substituent, the [arukeniru] basis of the carbon count 2-10 which is possible to possess the substituent, the [arukiniru] basis of the carbon count 2-10 which is possible to possess the substituent, the alkoxy group of the carbon count 1-10 which is possible to possess the substituent, the alkyl thio basis and the formyl basis of the carbon count 1-10 which is possible to possess the substituent, the alkyl carbonyl group of the carbon count 1-10 which is possible to possess the substituent, the alkoxy of the carbon count 1-10 which is possible to possess the substituentDisplaying the hetero aryl basis which the carbonyl group, the alkyl carbonyl oxy basis of the carbon count 1-10 which is possible to possess the substituent, the 1-5 which is chosen from the group which consists of the aryl basis, or the nitrogen atom, the oxygen atom, and the sulfur atom of the carbon count 6-30 which is possible to possess the substituent possesses the hetero atom and 5-8 member who the carbon atom is possible to possess the substituent of the 2-10 characteristic is done;
As for X, the 1-5 which is chosen from the group which consists of the nitrogen atom, the oxygen atom, the sulfur atom, the carbon atom, and the silicon atom displaying the linker basis which consists of the atomic group of 2 value to which consists of the atom and the hydrogen atom;
As for Z, the hydrogen atom, the basis which or it can connect adsorb to the surface of the solid baseplate;
Or the 1-15 which is chosen from the group which consists of the nitrogen atom, the oxygen atom, the sulfur atom, the carbon atom, the phosphorus atom, the halogen atom, and the silicon atom the end group which consists of the atomic group of 1 value to which consists of the atom and the hydrogen atom is displayed.)
So the Janus type [toripuchisen] derivative which is displayed.
[claim2]
2. General system [X in I], - CH [2] -, - CH=CH-, - O-, or - NR (6)- (here, R as for (6), displays the hydrogen atom, or the alkyl group of the carbon count 1-4.)So it is the basis of 2 value which is displayed, in claim 1 the Janus type [toripuchisen] derivative of statement.
[claim3]
3. General system [R in I] (1), from carbon count 2 the alkylene basis of 30, from carbon count 2 the [arukeniren] basis of 30, from carbon count 2 the [arukiniren] basis of 30, containing the aryl ring of 30 from carbon count, 6 it is the [ariren] basis of 2 value of 60 from the carbon count 6 which becomes, in claim 1 or 2 the Janus type [toripuchisen] derivative of statement.
[claim4]
4. General system [Z in I], the hydrogen atom, the halo alkyl group of the carbon count 1-10, the [arukeniru] basis of the carbon count 2-10 and the [arukiniru] basis of the carbon count 2-10, hydroxyl group, - COOR (7) (here, R (7), displays the alkyl group of the carbon count 1-5 which is possible to possess the hydrogen atom, or the substituent.)- N (R (8))[2] (Here, R (8), equality or it is possible to differ, the hydrogen atom, the aryl basis of the carbon count 6-30 which is possible to possess the alkyl group, or the substituent of the carbon count 1-5 which is possible to possess the substituent is displayed.)Or, - P (=O) (OR (15))[2] (Here, R (15), becoming independent respectively, the hydrogen atom, from carbon count 1 you display the aryl basis of 12 from the alkyl group, or carbon count 6 of 10.)So it is, from claim 1 either of 3 in one section the Janus type [toripuchisen] derivative of statement.
[claim5]
5. General system [R in I] (4), the hydrogen atom and the halogen atom, hydroxyl group, the nitro group, is the aryl basis of the carbon count 6-30 which is possible to possess the alkoxy group, or the substituent of the carbon count 1-10 which is possible to possess the substituent, from claim 1 either of 4 in one section the Janus type [toripuchisen] derivative of statement.
[claim6]
6. R (2), is the alkyl group of 4 from carbon count 1, from claim 1 either of 5 in one section the Janus type [toripuchisen] derivative of statement.
[claim7]
7. R (3), the basis - R (1)-Z (R as for (1) and Z the description above displays the basis which is done.)So it is, from claim 1 either of 6 in one section the Janus type [toripuchisen] derivative of statement.
[claim8]
8. From claim 1 the Janus type [toripuchisen] derivative of statement, lining up self-contained in either of 7, the membrane which becomes.
[claim9]
9. The substituent which the membrane, three of the [toripuchisen] framework the benzene ring which is arranged pinnately accumulates to nested condition, at the same time has connected to the same direction of the benzene ring of the [toripuchisen] framework lining up in the same direction, it is the membrane which was accumulated, in claim 8 the membrane of statement.
[claim10]
10. The membrane, is the multilayer membrane, in claim 8 or 9 the membrane of statement.
[claim11]
11. The membrane, is the monomolecular film, in claim 8 or 9 the membrane of statement.
[claim12]
12. From claim 8 either of 11 the structure which in one section possesses the membrane of statement on the surface of the solid baseplate.
[claim13]
13. The structure, is something which forms the portion of the electronic device, in claim 12 the structure of statement.
[claim14]
14. The electronic device is, the thin film transistor (TFT), in claim 13 the structure of statement.
[claim15]
15. From claim 1 either of 7 the Janus type [toripuchisen] derivative of statement is melted in the solvent in one section, whether the particular solution is applied to the surface of the solid baseplate or the method of soaking the solid baseplate in the particular solution, drying next and becoming, producing the membrane of the Janus type [toripuchisen] derivative.
[claim16]
16. Furthermore, annealing doing the membrane which is dried, it becomes, in claim 15 production method of statement.
[claim17]
17. The solvent, is the polar solvent, in claim 15 or 16 production method of statement.
[claim18]
18. The substituent which the membrane, three of the [toripuchisen] framework the benzene ring which is arranged pinnately accumulates to nested condition, at the same time has connected to the same direction of the benzene ring of the [toripuchisen] framework lining up in the same direction, it is the membrane which was accumulated, from claim 15 either of 17 in one section production method of statement.
[claim19]
19. The membrane, is the multilayer membrane, from claim 15 either of 18 in one section production method of statement.
[claim20]
20. The membrane, is the monomolecular film, from claim 15 either of 18 in one section production method of statement.
[claim21]
21. From claim 1 either of 7 the Janus type [toripuchisen] derivative of statement is melted in the solvent in one section, whether the particular solution is applied to the surface of the solid baseplate or it soaks the solid baseplate in the particular solution, dries next and becomes, on the surface of the solid baseplate the aforementioned general system [the method of producing the structure where the membrane of the Janus type [toripuchisen] derivative which is displayed with I] was formed.
[claim22]
22. From claim 8 either of claim 11 the Janus type [toripuchisen] derivative of statement lining up self-contained in one section, containing the membrane which becomes as the component, the electronic device which becomes.
[claim23]
23. The electronic device, is the transistor, in claim 22 the electronic device of statement.
[claim24]
24. The transistor, is the thin film transistor, in claim 23 the electronic device of statement.
  • 出願人(英語)
  • ※2012年7月以前掲載分については米国以外のすべての指定国
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • 発明者(英語)
  • FUKUSHIMA TAKANORI
  • SHOJI YOSHIAKI
  • ISHIWARI FUMITAKA
  • SEKITANI TSUYOSHI
  • SOMEYA TAKAO
国際特許分類(IPC)
指定国 (WO201610061)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
参考情報 (研究プロジェクト等) ERATO SOMEYA Bio-Harmonized Electronics AREA
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