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Mayenite-type compound containing imide anion, and method for producing same

Foreign code F170009048
File No. J1014-11WO
Posted date 2017年4月26日
Country アメリカ合衆国
Application number 201515123602
Gazette No. 20170072382
Gazette No. 10016742
Date of filing 平成27年2月12日(2015.2.12)
Gazette Date 平成29年3月16日(2017.3.16)
Gazette Date 平成30年7月10日(2018.7.10)
International application number JP2015053861
International publication number WO2015133240
Date of international filing 平成27年2月12日(2015.2.12)
Date of international publication 平成27年9月11日(2015.9.11)
Priority data
  • 特願2014-044716 (2014.3.7) JP
  • 2015WO-JP53861 (2015.2.12) WO
Title Mayenite-type compound containing imide anion, and method for producing same
Abstract (US10016742)
The invention related to a material that can stably hold an imide anion (NH2-) therein even in the atmosphere or in a solvent, and a method for synthesizing the material and a use of the material.
A mayenite-type compound into which imide anions are incorporated at a concentration of 1×1018 cm-3 or more are provided.
The mayenite-type compound can be produced by heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450 to 700° C. and at a pressure of 30 to 100 MPa.
The compound has properties such that active imide anions can be easily incorporated into the compound and the active imide anions can be easily released in the form of ammonia from the compound, and the compound has chemical stability.
Scope of claims [claim1]
1. A mayenite-type compound, wherein imide anions are incorporated into the mayenite-type compound at a concentration of 1 * 1018 cm-3 or more.
[claim2]
2. A method for producing the mayenite-type compound according to claim 1 comprising: heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450 deg. C. to 700 deg. C. and at a pressure of 30 to 100 MPa.
[claim3]
3. An imide anion supplying material comprising the mayenite-type compound according to claim 1.
[claim4]
4. An ammonia supplying material comprising the mayenite-type compound according to claim 1.
  • Inventor, and Inventor/Applicant
  • Hosono Hideo
  • Hayashi Fumitaka
  • Yokoyama Toshiharu
  • Kitano Masaaki
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • TOKYO INSTITUTE OF TECHNOLOGY
IPC(International Patent Classification)
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