Organic optical material

外国特許コード	F210010322
整理番号	AF29-06WO
掲載日	2021年2月1日
出願国	アメリカ合衆国
出願番号	201816641112
公報番号	20200284946
出願日	平成30年8月24日(2018.8.24)
公報発行日	令和2年9月10日(2020.9.10)
国際出願番号	JP2018031419
国際公開番号	WO2019039597
国際出願日	平成30年8月24日(2018.8.24)
国際公開日	平成31年2月28日(2019.2.28)
優先権データ	特願2017-161912 (2017.8.25) JP 特願2018-037356 (2018.3.2) JP 2018JP31419 (2018.8.24) WO
発明の名称 （英語）	Organic optical material
発明の概要（英語）	Provided is a novel donor-acceptor type compound which emits light even in a solid state. The present invention provides an organic optical material comprising a complex formed from (1) a conjugated molecule having (a) at least one electron donating site, (b) at least one electron accepting site, and (c) at least one conjugated site in the same molecule and (2) a compound having a proton donating property or an electron pair accepting property, the complex having a non-covalent interaction at the electron accepting site, wherein the complex is solid at ordinary temperature; and the organic optical material has a property of emitting light having a maximum fluorescence wavelength which causes a Stokes shift having a value corresponding to 5% or more of the value of a maximum absorption wavelength from the maximum absorption wavelength toward the long wavelength side.
従来技術、競合技術の概要（英語）	BACKGROUND OF THE INVENTION Light emitting organic compounds are used in a wide range of fields such as biological labeling materials, organic electronics materials, chemical sensors, and organic lasers. Novel light emitting materials are under active research and development. In particular, fluorescent organic compounds which emit light by irradiation with X-ray, ultraviolet ray, or visible light may be utilized in organic fluorescent coatings, etc., in addition to the purposes described above. However, most of molecules generally used as light emitting organic materials are robust and highly planar molecules. Therefore, such molecules intensely emit light in a solution because of less contact or interference between the molecules. By contrast, the molecules in a solid state such as a crystalline state often drastically reduce light emission efficiency because the energy of a released electromagnetic wave is attenuated by the influence of its neighboring planar molecules. Since the light emitting organic materials may be used in a solid state in terms of application, an important challenge thereto is to develop materials which intensely emit light not only in a solution but in a solid state. Many donor-acceptor type compounds have been reported and are known to exhibit diverse characteristics. Patent Literature 1 discloses a fluorescence emitting compound comprising a nitrogen-containing aromatic ring having high light emission efficiency not only in a solution state but in a solid state. Non Patent Literature 1 states that the fluorescence wavelength of a so-called donor-acceptor type compound in which the donor and the acceptor are conjugated with each other can be controlled by causing hydrochloric acid, trifluoroacetic acid, or boron tribromide as an activator to react with the compound. Non Patent Literature 2 describes various analyses conducted by allowing a boron-containing compound to act on a compound consisting of a dimethylamino group and a pyridine ring, which results in a finding that a dipole moment is increased through the reaction of the nitrogen atom of the pyridine ring with the boron atom. However, the literature does not disclose influence on a fluorescence wavelength.
特許請求の範囲（英語）	[claim1] 1: An organic optical material comprising a complex formed from (1) a conjugated molecule having (a) at least one electron donating site, (b) at least one electron accepting site, and (c) at least one conjugated site in the same molecule and (2) a compound having a proton donating property or an electron pair accepting property, the complex having a non-covalent interaction at the electron accepting site, wherein the complex is solid at ordinary temperature; and the organic optical material exhibits a property of emitting light having a maximum fluorescence wavelength which causes a Stokes shift of 5% or more of the value of a maximum absorption wavelength from the maximum absorption wavelength toward the long wavelength side when the conjugated molecule and the compound having a proton donating property or an electron pair accepting property form the complex. 2-34. (canceled)
発明者/出願人（英語）	KUNINOBU YOICHIRO KANAI MOTOMU YAMAKAWA TAKESHI YOSHIGOE YUSUKE WANG ZIJIA NAGASHIMA HIDEO TAHARA ATSUSHI JAPAN SCIENCE AND TECHNOLOGY AGENCY
国際特許分類(IPC)	G02B   1/04      有機物質，例．合成樹脂，で作られたもの C07D 213/18      その塩 C07D 213/30      酸素原子 C07D 219/06      酸素原子 C07D 401/12      鎖結合として異種原子を含有する鎖により結合しているもの C07D 417/12      鎖結合として異種原子を含有する鎖により結合しているもの C07F   5/02      ホウ素化合物 C07F   7/18      １個以上のＣ－Ｓｉ結合と１個以上のＣ－Ｏ－Ｓｉ結合をもつ化合物
参考情報 （研究プロジェクト等）	CREST Creation of Innovative Functions of Intelligent Materials on the Basis of the Element Strategy AREA