Electrolysis cell and electrolysis device
| 外国特許コード | F210010336 |
|---|---|
| 整理番号 | J1014-32WO |
| 掲載日 | 2021年2月2日 |
| 出願国 | 大韓民国 |
| 出願番号 | 20207027363 |
| 公報番号 | 20200135364 |
| 出願日 | 平成31年3月28日(2019.3.28) |
| 公報発行日 | 令和2年12月2日(2020.12.2) |
| 国際出願番号 | JP2019013888 |
| 国際公開番号 | WO2019189701 |
| 国際出願日 | 平成31年3月28日(2019.3.28) |
| 国際公開日 | 令和元年10月3日(2019.10.3) |
| 優先権データ |
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| 発明の名称 （英語） |
Electrolysis cell and electrolysis device
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| 発明の概要（英語） | Provided are an electrolysis cell and an electrolysis device capable of easily electrolyzing carbon dioxide into carbon monoxide and oxygen with low activation energy. A carbon dioxide electrolysis cell of the present invention includes a cathode, an anode, and a solid electrolyte having oxide ion conductivity. The electrolytic cell according to claim 1, wherein the cathode is (a) or (b) below. The mayenite composite includes (a) a metal and a first mayenite type compound; and (b) a metal and a second mayenite type compound, wherein the second mayenite type compound includes a mayenite type compound having electron conductivity. |
| 従来技術、競合技術の概要（英語） |
BACKGROUND ART Research of carbon dioxide immobilization and carbon dioxide decomposition is actively conducted according to the reduction of greenhouse effect gas on the global scale (Paris Agreement), among which electrolysis is noticed as one of new options. For example, when the molten salt is used as the electrolyte and the co2 The gas was mixed with solid carbon and O2 A method for decomposing into gases has been proposed (for example, Patent Document 1). In addition, ZrO2 To is Y2O3 By weight of a compound represented by the following general formula (1) is added as an electrolyte (hereinafter also referred to as "YSZ"). |
| 特許請求の範囲（英語） |
[claim1] 1. An electrolysis cell comprising: a cathode; an anode; and a solid electrolyte having oxide ion conductivity, wherein the cathode is (a) or (b) below. The present invention relates to: (a) a metal and a first mayenite type compound; (b) a metal and a second mayenite type compound, wherein the second mayenite type compound includes a mayenite type compound having electron conductivity, and wherein the first mayenite type compound and the second mayenite type compound include 12CaO · 7Al.2O3 The first mayenite type compound and the second mayenite type compound may be the same or different, and the mayenite type compound contains Al and at least one element selected from the group consisting of Ca and Sr, and a total of CaO and SrO in terms of oxide and Al2O3 The molar ratio of (a) to (b) is 12.6: 6.4 to 11.7: 7.3. [claim2] 2. The mayenite type compound according to claim 1, wherein the mayenite type compound comprises: (i) 0 to 17 mol% in total of at least one selected from the group consisting of b, Si, and Ge in terms of oxides with respect to the mayenite type compound; (ii) 0 to 17 mol% in total of at least one selected from the group consisting of Li, 0 to 5 mol% in total in terms of oxides with respect to the mayenite type compound; (iii) 0 to 10 mol% in total in terms of oxides with respect to the mayenite type compound of at least one selected from the group consisting of Mg and Ba; (iv) 0 to 5 mol% in total in terms of oxides with respect to the mayenite type compound of Ce, At least one rare-earth element selected from the group consisting of Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb, at least one transition metal element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Pd, Ir and Pt, And at least one or more typical metal elements selected from the group consisting of Zn, Cd, In, and Sn in a total amount of 0 to 8 mol% in terms of oxides with respect to the mayenite compound. [claim3] 3. The electrolysis cell according to claim 1, wherein the solid electrolyte is a third mayenite type compound. Here, the third mayenite type compound has a composition represented by 12CaO · 7Al2O3 The third mayenite type compound may be the same as or different from the first mayenite type compound or the second mayenite type compound. [claim4] 4. The electrolysis cell according to claim 1, wherein the anode is the first mayenite type compound or the second mayenite type compound. [claim5] 5. The electrolysis cell according to claim 1, wherein the electrolysis cell is for decomposing carbon dioxide. [claim6] 6. An electrolysis device comprising the electrolysis cell according to claim 1. [claim7] 7. A method for decomposing carbon dioxide using the electrolysis device according to claim 6. |
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