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Method for separating and recovering lignin derivatives

外国特許コード F110003546
整理番号 B74-01WO
掲載日 2011年6月29日
出願国 アメリカ合衆国
出願番号 92178806
公報番号 20090209739
公報番号 8012356
出願日 平成18年6月6日(2006.6.6)
公報発行日 平成21年8月20日(2009.8.20)
公報発行日 平成23年9月6日(2011.9.6)
国際出願番号 JP2006311263
国際公開番号 WO2006132199
国際出願日 平成18年6月6日(2006.6.6)
国際公開日 平成18年12月14日(2006.12.14)
優先権データ
  • 特願2005-167103 (2005.6.7) JP
  • 2006WO-JP311263 (2006.6.6) WO
発明の名称 (英語) Method for separating and recovering lignin derivatives
発明の概要(英語) (US8012356)
An object of the present invention is to provide a technique for separation/collection of a lignin derivative which is useful for the separation of a lignin derivative having a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-diphenylpropane unit from a mixture system containing the lignin derivative.
In the Present invention, a lignin derivative having a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-dipheylpropane unit is allowed to contact with a metal oxide in a liquid medium, thereby separating the lignin derivative in the form retained on the metal oxide.
特許請求の範囲(英語) [claim1]
1. A method for separating a lignin derivative, the method comprising: contacting the lignin derivative with a metal oxide in a liquid medium,
separating the metal oxide carrying the lignin derivative from the liquid medium, and
recovering the lignin derivative from the metal oxide under an alkali condition to prevent alkali degradation of the lignin derivative,
wherein the lignin derivative has a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-diphenylpropane unit.
[claim2]
2. The method as in claim 1, wherein the metal oxide is an oxide of one or more metals selected from the group consisting of titanium, zinc, iron, cobalt, nickel, copper, tin, indium, lead, and niobium.
[claim3]
3. The method as in claim 2, wherein the metal oxide comprises a titanium oxide.
[claim4]
4. The method as in claim 1, wherein the metal oxide comprises a semiconductor material.
[claim5]
5. The method as in claim 1, wherein the metal oxide comprises the metal oxide particle of average particle size less than or equal to 300 nm.
[claim6]
6. The method as in claim 1, wherein the liquid medium is selected from the group consisting of an aqueous medium, a non-aqueous medium and mixture thereof.
[claim7]
7. The method as in claim 1, wherein the lignin derivative is dissolved or dispersed in the liquid medium.
[claim8]
8. The method as in claim 1, wherein the lignin derivative is one or more lignin derivatives selected from the group consisting of following (a) to (d): (a) a ligno-phenol derivative which is a phenol-derivative of lignin, the ligno-phenol derivative obtainable by solvating a lignin containing material with a phenol compound and then mixing the solvated lignin containing material with an acid;
(b) a secondary derivative obtainable by modifying the ligno-phenol derivative with a functional group selected from the group consisting of an acyl group, a carboxy group, an amido group, and a cross-linking group;
(c) a secondary derivative obtainable by treating the ligno-phenol derivative with an alkali; and
(d) a higher order derivative obtainable by modifying the ligno-phenol derivative with at least two modifications selected from the following modifications: introduction of an acyl group, introduction of a carboxy group, introduction of an amido group, introduction of a cross-linking group and an alkali-treatment.
[claim9]
9. The method as in claim 8, the lignin derivative comprises the lignin derivative (a).
[claim10]
10. The method as in claim 8, the lignin derivative comprises the lignin derivative (b).
[claim11]
11. The method as in claim 8, the lignin derivative comprises the lignin derivative (c).
[claim12]
12. The method as in claim 1, wherein the recovering is performed at a temperature of less than or equal to 60 deg. C.
[claim13]
13. A method for producing a lignin derivative comprising: contacting the lignin derivative with a metal oxide in a liquid medium,
separating the metal oxide carrying the lignin derivative from the liquid medium, and
recovering the lignin derivative from the metal oxide under an alkali condition to prevent alkali degradation of the lignin derivative,
wherein the lignin derivative has a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-diphenylpropane unit.
[claim14]
14. The method as in claim 13, wherein the lignin derivative is a ligno-phenol derivative of a lignin obtainable by solvating a lignin containing material with a phenol compound and then mixing the solvated lignin containing material with an acid; and during the separation step the ligno-phenol derivative is contacted with the metal oxide added to the liquid medium prior to the formation of the ligno-phenol derivative.
[claim15]
15. The method as in claim 13, wherein the lignin derivative is a ligno-phenol derivative of a lignin obtainable by solvating a lignin containing material with a phenol compound and then mixing the solvated lignin containing material with an acid; and during the separation step the ligno-phenol derivative is contacted with the metal oxide added to the liquid medium after the formation of the ligno-phenol derivative.
[claim16]
16. A method of purifying a lignin derivative, the method comprising: contacting the lignin derivative with a metal oxide in a liquid medium,
separating the metal oxide carrying the lignin derivative from the liquid medium, and
recovering the lignin derivative from the metal oxide under an alkali condition to prevent alkali degradation of the lignin derivative,
wherein the lignin derivative has a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-diphenylpropane unit.
[claim17]
17. A method for recovering a lignin derivative from a composite material containing thereof, the method comprising: contacting the lignin derivative with a metal oxide in a liquid medium
separating the metal oxide carrying the lignin derivative from the liquid medium, and
recovering the lignin derivative from the metal oxide under an alkali condition to prevent alkali degradation of the lignin derivative,
wherein the lignin derivative has a 1,1-diphenylpropane unit and/or a unit derived from the 1,1-diphenylpropane unit.
[claim18]
18. The method as in claim 17, wherein the composite material comprises a used product.
  • 発明者/出願人(英語)
  • FUNAOKA MASAMITSU
  • AOYAGI MITSURU
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
国際特許分類(IPC)
参考情報 (研究プロジェクト等) SORST Selected in Fiscal 2004
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