9-AZANORADAMANTANE N-OXYL COMPOUND AND METHOD FOR PRODUCING SAME, AND ORGANIC OXIDATION CATALYST AND METHOD FOR OXIDIZING ALCOHOLS USING 9-AZANORADAMANTANE N-OXYL COMPOUND
外国特許コード | F130007673 |
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整理番号 | S2012-0477-N0 |
掲載日 | 2013年10月17日 |
出願国 | 世界知的所有権機関(WIPO) |
国際出願番号 | 2013JP054554 |
国際公開番号 | WO 2013/125688 |
国際出願日 | 平成25年2月22日(2013.2.22) |
国際公開日 | 平成25年8月29日(2013.8.29) |
優先権データ |
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発明の名称 (英語) | 9-AZANORADAMANTANE N-OXYL COMPOUND AND METHOD FOR PRODUCING SAME, AND ORGANIC OXIDATION CATALYST AND METHOD FOR OXIDIZING ALCOHOLS USING 9-AZANORADAMANTANE N-OXYL COMPOUND |
発明の概要(英語) |
The invention relates to an organocatalyst for oxidizing alcohols a primary alcohol is selectively oxidized in a polyol substrate having a plurality of alcohols under environmentally-friendly conditions. The organic oxidation catalyst for oxidizing alcohols has an oxygen atom bonded to a nitrogen atom of an azanoradamantane skeleton and at least one alkyl group at positions 1 and 5. The invention provides an oxidation catalyst having higher activity than TEMPO, which is an existing oxidation catalyst, in the selective oxidation reaction of primary alcohols, and better selectivity than AZADO and 1-Me-AZADO. This DMN-AZADO can be applied to the selective oxidation reaction of primary alcohols that contributes to shortening the synthesizing process for pharmaceuticals, pharmaceutical raw materials, agricultural chemicals, cosmetics, organic materials, and other such high value-added organic compounds. |
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国際特許分類(IPC) |
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日本語項目の表示
発明の名称 | アルコール酸化触媒および酸化手法 |
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『 9-AZANORADAMANTANE N-OXYL COMPOUND AND METHOD FOR PRODUCING SAME, AND ORGANIC OXIDATION CATALYST AND METHOD FOR OXIDIZING ALCOHOLS USING 9-AZANORADAMANTANE N-OXYL COMPOUND 』に関するお問合せ
- 国立大学法人東北大学 産学連携機構知的財産部
- URL: http://www.rpip.tohoku.ac.jp/jp/
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E-mail:
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