TOP > 外国特許検索 > CROSS-COUPLING METHOD, AND METHOD FOR PRODUCING ORGANIC COMPOUND USING SAID CROSS-COUPLING METHOD

CROSS-COUPLING METHOD, AND METHOD FOR PRODUCING ORGANIC COMPOUND USING SAID CROSS-COUPLING METHOD コモンズ

外国特許コード F160008709
整理番号 NU-647
掲載日 2016年4月1日
出願国 世界知的所有権機関(WIPO)
国際出願番号 2016JP053310
国際公開番号 WO 2016125845
国際出願日 平成28年2月4日(2016.2.4)
国際公開日 平成28年8月11日(2016.8.11)
優先権データ
  • 20150-021444 JP
  • 201562272038 (2015.12.28) US
発明の名称 (英語) CROSS-COUPLING METHOD, AND METHOD FOR PRODUCING ORGANIC COMPOUND USING SAID CROSS-COUPLING METHOD コモンズ
発明の概要(英語) An aromatic compound and a sulfonimide compound can be cross-coupled safely and easily using a wide variety of substrates by reacting an aromatic compound and a specific sulfonimide compound in the presence of a copper compound and a specific ligand.
従来技術、競合技術の概要(英語) BACKGROUND ART
To introduce an amino group in aromatic compounds and arylamine compounds, photosensitive, transistor, light emitting diodes, electronic devices such as organic EL materials, solar cell material, fluorescent material, is useful as a pharmaceutical material or the like from, a simple synthesis method is demanded. For example, of the following compounds are (1) porphyrin-sensitized solar cell and be used as, drug resistance of the following compounds are (2) used as antibiotics for bacteria and, a perovskite of the following compounds are (3) used as the hole transport material sensitized solar cells and, living cells of the following compounds are (4) super-resolution imaging of the fluorescent dye molecules as used.
This-arylamine compounds, alkylated aromatic compound with respect to the sulfonimide, magnesium metal in ethanol in the presence of a reductive deprotection can be easily synthesized by (for example, such as non-patent document 1) can be, sulfonimide-alkylated aromatic compound can be synthesized by a simple method is demanded.
Conventionally, at the time of synthesizing the compound of various, kinds of matrix 2 to the raw material compound, are reacted in the presence of suitable catalysts (cross-coupling reaction) method are known and, for compounds aromatic sulfonimide, cross-coupling reaction as long as it can be synthesized using, conveniently sulfonimide-alkylated aromatic compound can be obtained, as a result arylamine compounds can be easily synthesized considered.
Of the sulfonimide-alkylated aromatic compound such as the synthesis method, for example, aromatic compounds, and N- fluorobenzenesulphonimide (NFSI), bis (2, 2' - bipyridyl) and a palladium catalyst and silver perchlorate (II) (Ag (bipy)2 ClO4) by reacting in the presence of, to the aromatic compound are introduced into the imide group is known (for example, such as non-patent document 1). In addition, sulfonimide as the synthesis method of aromatic compounds, thiophene compounds, furan, pyrrole compound such as a five-membered ring of the heteroaromatic ring compound, and (NFSI) fluorobenzenesulphonimide N -, the presence of copper catalyst, without using a ligand, by the reaction of, to the aromatic compound introduced into the imide group is also known (for example, such as non-patent document 2).
  • 出願人(英語)
  • ※2012年7月以前掲載分については米国以外のすべての指定国
  • NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITY
  • 発明者(英語)
  • ITAMI KENICHIRO
  • MURAKAMI KEI
  • KAWAKAMI TAKAHIRO
  • MUSAEV DJAMALADDIN G
  • HAINES BRANDON E
国際特許分類(IPC)
指定国 National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
名古屋大学の公開特許情報を掲載しています。ご関心のある案件がございましたら、下記まで電子メールでご連絡ください。

PAGE TOP

close
close
close
close
close
close