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COORDINATION POLYMER COMPOUND, POROUS MATERIAL, ANION REMOVER, AND ANION REMOVAL METHOD

Foreign code F160008813
File No. (S2014-1552-N0)
Posted date Aug 5, 2016
Country WIPO
International application number 2015JP075748
International publication number WO 2016043122
Date of international filing Sep 10, 2015
Date of international publication Mar 24, 2016
Priority data
  • P2014-187979 (Sep 16, 2014) JP
Title COORDINATION POLYMER COMPOUND, POROUS MATERIAL, ANION REMOVER, AND ANION REMOVAL METHOD
Abstract A coordination polymer compound including: a coordination polymer backbone having a structure of a plurality of metal ions such as Cu2+ crosslinked by ligands represented by any of formula (1) to formula (4); a plurality of capsule-type compounds comprising anions encapsulated as encapsulated ions in a capsule backbone represented by formula (C); anions as crosslinking ions for crosslinking each coordination polymer backbone and a plurality of capsule-type compounds; and anions as counter ions to the coordination polymer backbone and plurality of capsule-type compounds. R1-R8, R21-R28, and R31-R38 represent H, a methyl group, or methoxy group, L represents a ligand represented by any of formula (1) to formula (4), and M represents Cu2+.
Scope of claims [claim1]
1.  Cu 2 +, Fe 2 +, Ni 2 +, Co 2 +, Pt 2 +, Pd 2+, or Zn 2+ plurality of metal ions which are is represented by the following formulas (1) to the following cross-linked by a bidentate ligand represented by any one of formula (4), and each of said plurality of metal ions have been planar four-coordinate by the bidentate ligand of 4 molecular structure a cationic coordination polymer backbone having,  Capsules skeleton represented by the following formula (C), anion, which are contained as encapsulated ion, a plurality of cationic capsule compound,  And an anion as a crosslinking ion to crosslink with each of the cationic coordination polymer skeleton and the plurality of cationic capsule compound,  And an anion as a counterion to the cationic coordination polymer backbone and said plurality of cationic capsule compound, Coordination polymer compound containing a. [Image] Wherein (1) to (4), R 1 ~ R 8, R 21 ~ R 28, and R 31 ~ R 38 are each independently a hydrogen atom represents methyl group, or methoxy group.  In the formula (C), L represents a bidentate ligand represented by any one of formulas (1) to (4), two M are each independently, Cu 2 +, Fe 2 +, Ni 2 +, Co 2 +, Pt 2 +, Pd 2+, or Zn 2+ represents, the dashed line represents a coordinate bond. ]
[2]
[claim2]
2.  Anions as the inclusion ions, anions as the cross-linking ion, and anions as the counterion, independently, Cl -, Br -, or I - claim 1 which is coordination polymer compound according to.
[3]
[claim3]
3.  Wherein the plurality of metal ions of the cationic coordination polymer backbone and,  Two of M in the above formula (C) is, Coordination polymer compound according to claim 1 or claim 2 which is the same species.
[4]
[claim4]
4.  Wherein the plurality of metal ions of the cationic coordination polymer backbone and,  Two of M in the above formula (C) is, Coordination polymer compound according to claim 3, which is a Cu 2+.
[5]
[claim5]
5.  Anions as the inclusion ions, anions as the cross-linking ion, and anions as the counterion, Coordination polymer compound according to any one of claims 1 to 4 which is the same species.
[6]
[claim6]
6.  Anions as the inclusion ions, anions as the cross-linking ion, and anions as the counterion, Cl - or Br - coordination polymer compound according to claim 5 which is a.
[7]
[claim7]
7.  R 5 in the formula (1) ~ R 8,  R 5 in the formula (2) in ~ R 8,  The formula (3) of R 25, R 26, and R 28, as well as  R 25 in the formula (4) in, R 26, and R 28, Coordination polymer compound according to any one of claims 1 to 6 are methyl groups.
[8]
[claim8]
8.  In the formula (1) of R 1 ~ R 4 and R 31 ~ R 35,  The formula (2) of the R 1 ~ R 4 and R 36 ~ R 38,  The formula (3) of R 21 ~ R 24, R 27, and R 31 ~ R 35, as well as  The formula (4) of R 21 ~ R 24, R 27, and R 36 ~ R 38, Coordination polymer compound according to any one of claims 1 to 7 is a hydrogen atom.
[9]
[claim9]
9.  Bidentate ligand of the cationic coordination polymer backbone and,,  Four L in the above formula (C) is, Coordination polymer compound according to any one of claims 1 to 8 is a bidentate ligand represented by the formula (1).
[10]
[claim10]
10.  The porous material comprising a coordination polymer compound according to any one of claims 1 to 9.
[11]
[claim11]
11.  Anionic removal agent containing a porous material as an active ingredient the coordination polymer compound or claim 10 according to any one of claims 1 to 9.
[12]
[claim12]
12.  NO3 -, ClO4 -, BF4 -, CF3SO3 -, and PF6 - and a liquid sample containing at least one anion selected from the group consisting of, according to Claim 11 by contacting and anion removing agent, and the negative ions contained in the liquid sample, the anion removing method comprising the step of removing from said liquid sample.
[13]
[claim13]
13.  The liquid sample is at least NO3 - Anion removal method according to claim 12 comprising a.
  • Applicant
  • ※All designated countries except for US in the data before July 2012
  • SHIZUOKA UNIVERSITY
  • Inventor
  • KONDO MITSURU
  • SONE ERIKO
IPC(International Patent Classification)
Specified countries National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
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