MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC RESIN
| 外国特許コード | F170008969 |
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| 整理番号 | K10505WO |
| 掲載日 | 2017年3月13日 |
| 出願国 | 世界知的所有権機関（ＷＩＰＯ） |
| 国際出願番号 | 2015JP082143 |
| 国際公開番号 | WO 2016080358 |
| 国際出願日 | 平成27年11月16日(2015.11.16) |
| 国際公開日 | 平成28年5月26日(2016.5.26) |
| 優先権データ |
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| 発明の名称 （英語） | MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC RESIN |
| 発明の概要（英語） | Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) |
| 特許請求の範囲（英語） |
[claim1] 1. The below-mentioned formula (1) or formula the [mekanokuromitsuku] luminescent material which is displayed with (2). (In formula, Y [1] and Y [2] is displayed with formula (1) to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which, being the same and it is possible to differ. Z [1] and Z [2] to display the polymerization basis, being the same and it is possible. to differ,) (In formula, Y [1] and Y [2] is displayed with formula (2) to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which, being the same and it is possible to differ. Z [1] and Z [2] to display the polymerization basis, being the same and it is possible. to differ,) [claim2] 2. The description above Y [1] and Y [2], in the claim 1 which is selected from the substituent below the [mekanokuromitsuku] luminescent material of statement. (R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.) [claim3] 3. The aforementioned polymerization basis Z [1] and Z [2], in the claim 1 which is selected from the substituent below or 2 the [mekanokuromitsuku] luminescent material of statement. (The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good. The above-mentioned formula (3) and (4) R in [1] R of claim 2 [is similar to 1]. In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.) [claim4] 4. Either of the claim 1-3 the [mekanokuromitsuku] resin where in one section the [mekanokuromitsuku] luminescent material of statement has built a bridge in the polymer chain. [claim5] 5. In the claim 4 where the aforementioned [mekanokuromitsuku] resin is film condition or fibrous the [mekanokuromitsuku] resin of statement. [claim6] 6. In claim the tension sensor which includes the [mekanokuromitsuku] resin of statement 4 or 5. [claim7] 7. The below-mentioned formula (16) with chemical compound and the below-mentioned formula which are displayed (25) with the process which reacts the chemical compound which is displayed is included, The below-mentioned formula (26) with production method of the [mekanokuromitsuku] luminescent material which is displayed. (In formula, Y [1] and Y [2] formula (26) with to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which is displayed, being the same and it is possible to differ. Z [1] and Z [2] to display the polymerization basis, being the same and it is possible to differ. n displays the integer of the 0-3.) (In formula, Y Y [1] and Y [is the same as 2]. Z Z [1] or Z [is the same as 2].) (In formula, n displays the integer of the 0-3.) [claim8] 8. The description above Y [1] and Y [2], in the claim 7 which is selected from the substituent below production method of the [mekanokuromitsuku] luminescent material of statement. (R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.) [claim9] 9. The aforementioned polymerization basis Z [1] and Z [2], in the claim 7 which is selected from the substituent below or 8 production method of the [mekanokuromitsuku] luminescent material of statement. (The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good. The above-mentioned formula (3) and (4) R in [1] R of claim 8 [is similar to 1]. In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.) [claim10] 10. The description above n, 0 or 1 either of the claim 7-9 which is in one section production method of the [mekanokuromitsuku] luminescent material of statement. [claim11] 11. In the organic solvent, the below-mentioned formula (26) with the [mekanokuromitsuku] luminescent material which is displayed, the process which mixes polymerization characteristic monomer, and the catalyst or the initiator, Production method of the [mekanokuromitsuku] resin which is included. (In formula, Y [1] and Y [2] formula (26) with to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which is displayed, being the same and it is possible to differ. Z [1] and Z [2] to display the polymerization basis, being the same and it is possible to differ. n displays the integer of the 0-3.) [claim12] 12. The description above Y [1] and Y [2], in the claim 11 which is selected from the substituent below production method of the [mekanokuromitsuku] resin of statement. (R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3]. The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.) [claim13] 13. The aforementioned polymerization basis Z [1] and Z [2], in the claim 11 which is selected from the substituent below or 12 production method of the [mekanokuromitsuku] resin of statement. (The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good. The above-mentioned formula (3) and (4) R in [1] R of claim 12 [is similar to 1]. In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.) [claim14] 14. Description above n, 0 or 1 either of the claim 11-13 which is in one section production method of the [mekanokuromitsuku] resin of statement. |
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| 国際特許分類(IPC) |
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| 指定国 |
(WO201680358) National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW EAPO: AM AZ BY KG KZ RU TJ TM EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG |
| 参考情報 （研究プロジェクト等） | PRESTO Molecular technology and creation of new functions AREA |
日本語項目の表示
| 発明の名称 | メカノクロミック発光材料、該メカノクロミック発光材料を架橋したメカノクロミック樹脂、メカノクロミック発光材料の製造方法及びメカノクロミック樹脂の製造方法 |
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| 発明の概要 | 材料にかかるストレスをリアルタイムで可視化できるメカノクロミック樹脂及びメカノクロミック樹脂の合成に用いられるメカノクロミック発光材料を提供する。 下記式（１）又は式（２）で表されるメカノクロミック発光材料、及び該メカノクロミック発光材料を架橋したメカノクロミック樹脂でストレスをリアルタイムで可視化できる。 【化１】 （式中、Ｙ1及びＹ2は式（１）で表されるメカノクロミック発光材料の凝集を阻害する置換基を表し、同じであっても異なってもよい。Ｚ1及びＺ2は重合基を表し、同じであっても異なってもよい。） 【化２】（式中、Ｙ1及びＹ2は式（１）で表されるメカノクロミック発光材料の凝集を阻害する置換基を表し、同じであっても異なってもよい。Ｚ1及びＺ2は重合基を表し、同じであっても異なってもよい。） |
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