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MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC RESIN

Foreign code F170008969
File No. K10505WO
Posted date Mar 13, 2017
Country WIPO
International application number 2015JP082143
International publication number WO 2016080358
Date of international filing Nov 16, 2015
Date of international publication May 26, 2016
Priority data
  • P2014-233309 (Nov 18, 2014) JP
Title MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC RESIN
Abstract Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.)
Scope of claims [claim1]
1. The below-mentioned formula (1) or formula the [mekanokuromitsuku] luminescent material which is displayed with (2).
(In formula, Y [1] and Y [2] is displayed with formula (1) to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which, being the same and it is possible to differ.
Z [1] and Z [2] to display the polymerization basis, being the same and it is possible. to differ,)
(In formula, Y [1] and Y [2] is displayed with formula (2) to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which, being the same and it is possible to differ.
Z [1] and Z [2] to display the polymerization basis, being the same and it is possible. to differ,)
[claim2]
2. The description above Y [1] and Y [2], in the claim 1 which is selected from the substituent below the [mekanokuromitsuku] luminescent material of statement.
(R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.)
[claim3]
3. The aforementioned polymerization basis Z [1] and Z [2], in the claim 1 which is selected from the substituent below or 2 the [mekanokuromitsuku] luminescent material of statement.
(The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good.
The above-mentioned formula (3) and (4) R in [1] R of claim 2 [is similar to 1].
In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.)
[claim4]
4. Either of the claim 1-3 the [mekanokuromitsuku] resin where in one section the [mekanokuromitsuku] luminescent material of statement has built a bridge in the polymer chain.
[claim5]
5. In the claim 4 where the aforementioned [mekanokuromitsuku] resin is film condition or fibrous the [mekanokuromitsuku] resin of statement.
[claim6]
6. In claim the tension sensor which includes the [mekanokuromitsuku] resin of statement 4 or 5.
[claim7]
7. The below-mentioned formula (16) with chemical compound and the below-mentioned formula which are displayed (25) with the process which reacts the chemical compound which is displayed is included,
The below-mentioned formula (26) with production method of the [mekanokuromitsuku] luminescent material which is displayed.
(In formula, Y [1] and Y [2] formula (26) with to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which is displayed, being the same and it is possible to differ.
Z [1] and Z [2] to display the polymerization basis, being the same and it is possible to differ. n displays the integer of the 0-3.)
(In formula, Y Y [1] and Y [is the same as 2].
Z Z [1] or Z [is the same as 2].)
(In formula, n displays the integer of the 0-3.)
[claim8]
8. The description above Y [1] and Y [2], in the claim 7 which is selected from the substituent below production method of the [mekanokuromitsuku] luminescent material of statement.
(R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.)
[claim9]
9. The aforementioned polymerization basis Z [1] and Z [2], in the claim 7 which is selected from the substituent below or 8 production method of the [mekanokuromitsuku] luminescent material of statement.
(The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good.
The above-mentioned formula (3) and (4) R in [1] R of claim 8 [is similar to 1].
In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.)
[claim10]
10. The description above n, 0 or 1 either of the claim 7-9 which is in one section production method of the [mekanokuromitsuku] luminescent material of statement.
[claim11]
11. In the organic solvent, the below-mentioned formula (26) with the [mekanokuromitsuku] luminescent material which is displayed, the process which mixes polymerization characteristic monomer, and the catalyst or the initiator,
Production method of the [mekanokuromitsuku] resin which is included.
(In formula, Y [1] and Y [2] formula (26) with to display the substituent which obstructs the cohesion of the [mekanokuromitsuku] luminescent material which is displayed, being the same and it is possible to differ.
Z [1] and Z [2] to display the polymerization basis, being the same and it is possible to differ. n displays the integer of the 0-3.)
[claim12]
12. The description above Y [1] and Y [2], in the claim 11 which is selected from the substituent below production method of the [mekanokuromitsuku] resin of statement.
(R [1] -R [inside 7], optional one the polymerization basis Z [1] or Z [displays 2].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7], the direct condition, divergence condition or the annular alkyl group of H and the carbon count 1-20, the aryl basis of the carbon count 6-20, F, Cl and Br, I, CF [3], CCl [3], or OCH [displays 3].
The polymerization basis Z [1] or Z [2] R other than [1] -R [7] may be being the same, differing.)
[claim13]
13. The aforementioned polymerization basis Z [1] and Z [2], in the claim 11 which is selected from the substituent below or 12 production method of the [mekanokuromitsuku] resin of statement.
(The above-mentioned formula (3) and (4) in, X displays amide or ester, but it is not included and also the [te] is good.
The above-mentioned formula (3) and (4) R in [1] R of claim 12 [is similar to 1].
In addition, the type (3)- (13) R in direct condition, divergence condition or the annular alkyl group of the carbon count 1-20, displays the aryl basis of the carbon count 6-20, but R is not included and also the [te] is good. - Y [1] or Y [2] is displayed.)
[claim14]
14. Description above n, 0 or 1 either of the claim 11-13 which is in one section production method of the [mekanokuromitsuku] resin of statement.
  • Applicant
  • ※All designated countries except for US in the data before July 2012
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • Inventor
  • YABU HIROSHI
  • SAITO YUTA
  • SAITO SHOHEI
  • YAMAGUCHI SHIGEHIRO
  • NOBUSUE SHUNPEI
IPC(International Patent Classification)
Specified countries (WO201680358)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KN KP KR KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
Reference ( R and D project ) PRESTO Molecular technology and creation of new functions AREA
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