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POLYMER AND METHOD FOR PRODUCING SAME commons

Foreign code F170009099
File No. NU-675
Posted date Jun 1, 2017
Country WIPO
International application number 2017JP003037
International publication number WO 2017131190
Date of international filing Jan 27, 2017
Date of international publication Aug 3, 2017
Priority data
  • P2016-014380 (Jan 28, 2016) JP
Title POLYMER AND METHOD FOR PRODUCING SAME commons
Abstract Provided is a polymer which contains a polycyclic aromatic compound as a repeating unit and in which the polycyclic aromatic compound contained as a repeating unit is bonded to an adjacent polycyclic aromatic compound that is a repeating unit in such a way as to share one bond that constitutes a benzene ring in the polycyclic aromatic compound. The polymer is obtained through (co)polymerization of a polycyclic aromatic compound having a K region and a silole skeleton as a raw material or a polycyclic aromatic compound having a K region and a polycyclic aromatic compound having a silole skeleton as raw materials, is obtained using a method which has fewer steps and in which secondary reactions are suppressed, and can constitute a GNR in which the width and length are controlled. The repeating unit is preferably a repeating unit represented by general formula (1) [In the formula, * denotes the repeating unit site. m denotes an integer of 1 or higher. A denotes an aromatic ring having a K region. In cases where m is 2 or higher, the plurality of A moieties may be the same as, or different from, each other. R1 and R3 each denote a hydrogen atom. R2 and R4 may be the same as, or different from, each other, and each denote a branched chain alkyl group or a group represented by general formula (2) (In the formula, *, m, A, R1 and R3 are as described above. R2a denotes a branched chain alkyl group. At least one combination of R1 and R2a, R1 and A, and R3 and A may bond to each other to form a ring.) At least one combination of R1 and R2, R3 and R4, R1 and A, and R3 and A may bond to each other to form a ring.]
Scope of claims [claim1]
1. It repeats the polynuclear aromatic compound and makes the unit, in order to share one connection which forms the benzene ring in the aforementioned polynuclear aromatic compound, it connects the polynuclear aromatic compound as the said repetition unit, with the polynuclear aromatic compound as the repetition unit which it adjoins, the polymer.
[claim2]
2. (Also) you polymerize territory and the shiroru framework the polynuclear aromatic compound or the polynuclear aromatic compound which possesses the K territory and possesses the shiroru framework the polynuclear aromatic compound which possess the K as raw materials, in claim 1 the polymer of statement.
[claim3]
3. General system (1):
[In formula, * it repeats and shows the region. m shows the integer of 1 or more.
A shows the aromatic ring which possesses the K territory.
When m is integer of 2 or more, plural A being identical, are possible to differ.
R (1) and R (3) shows the hydrogen atom.
R (2) and R as for (4) equality or differing, the divergence chain alkyl group, or general system (2):
(In formula, *, m, A and R (1) and R (3) is the same to the description above.
R (2a) the divergence chain alkyl group is shown.
R (1) and R (2a), R (1) and A, and it connects at least the one R (3) and A is possible to form ring mutually.)
So the basis which is displayed is shown.
R (1) and R (2), R (3) and R (4), R (1) and A, and it connects at least the one R (3) and A is possible to form ring mutually. ]
So it possesses the repetition unit which is displayed, in claim 1 or 2 the polymer of statement.
[claim4]
4. The aforementioned repetition unit, general system (1A) - (1F):
[In formula, *, R (2a) and R (4a) it is the same to the description above.
Y equality or differing, shows CH or N. R (2b) and R (4b) equality or differing, it shows the divergence chain alkyl group. ]
It is the repetition unit which is displayed with in each case, in either of the claim 1-3 the polymer of statement.
[claim5]
5. The Kazuhei equal molecular weight is 10000 or more, in either of the claim 1-4 the polymer of statement.
[claim6]
6. Gurahuennanoribon which consists of the polymer of statement in either of the claim 1-5.
[claim7]
7. Width 0.5-10.0 nm and length is 10 nm or more, in claim 6 gurahuennanoribon of statement.
[claim8]
8. Being production method of the polymer of statement in either of the claim 1-5,
(1) the palladium compound and under the existing of o-kuroraniru, the process which reacts the K territory and the polynuclear aromatic compound which possesses the shiroru framework, or
(2) the palladium compound and under the existing of o-kuroraniru, the process which reacts with the polynuclear aromatic compound which possesses the K territory and the polynuclear aromatic compound which possesses the shiroru framework
It has, production method.
[claim9]
9. In the aforementioned process (1), the K territory and possesses the shiroru framework the polynuclear aromatic compound which, general system (3A) or (3B):
[In formula, A equality or differing, shows the aromatic ring which possesses the K territory.
R (1) and R (3) shows the hydrogen atom.
R (2a) and R (4a) equality or differing, it shows the divergence chain alkyl group.
R (1) and R (2a), R (3) and R (4a), R (1) and A, and it connects at least the one R (3) and A is possible to form ring mutually.
R (5) and, R (6) equality or differing, shows the hydrogen atom or the alkyl group. ]
So it is the chemical compound which is displayed, in claim 8 production method of statement.
[claim10]
10. In the aforementioned process (2), possesses the K territory the polynuclear aromatic compound which, general system (4):
[In formula, A equality or differing, shows the aromatic ring which possesses the K territory.
R (1) and R (3) shows the hydrogen atom.
R (2) and R as for (4) equality or differing, the divergence chain alkyl group, or general system (4A):
(In formula, A and R (1) and R (3) is the same to the description above.
R (2a) the divergence chain alkyl group is shown.
R (1) and R (2a), R (1) and A, and it connects at least the one R (3) and A is possible to form ring mutually.)
So the basis which is displayed is shown.
R (1) and R (2), R (3) and R (4), R (1) and A, and it connects at least the one R (3) and A is possible to form ring mutually. ]
So it is the chemical compound which is displayed, in claim 8 or 9 production method of statement.
[claim11]
11. In the aforementioned process (2), possesses the shiroru framework the polynuclear aromatic compound which, general system (5):
[In formula, B equality or differing, shows the aromatic ring which possesses the shiroru framework.
R (1) and R (3) shows the hydrogen atom.
R (2a) and R (4a) equality or differing, it shows the divergence chain alkyl group.
R (1) and R (2a), R (3) and R (4a), R (1) and B, and it connects at least the one R (3) and B is possible to form ring mutually.
R (5) and, R (6) equality or differing, shows the hydrogen atom or the alkyl group. ]
So it is the chemical compound which is displayed, in either of the claim 8-10 production method of statement.
[claim12]
12. The aforementioned process (1) and (2), is done under existing of the silver compound, in either of the claim 8-11 production method of statement.
[claim13]
13. The aforementioned silver compound, AgSbF [6] or AgBF [contains 4], in claim 12 production method of statement.
[claim14]
14. Amount used of the aforementioned silver compound, is the 0.5-5.0 mol vis-a-vis the polynuclear aromatic compound 1 mols which possess the aforementioned K territory and the polynuclear aromatic compound, possesses the aforementioned K territory the polynuclear aromatic compound, or the aforementioned shiroru framework which possess the shiroru framework, in claim 12 or 13 production method of statement.
[claim15]
15. Amount used of the aforementioned palladium compound, is the 0.07-5.0 mol vis-a-vis the polynuclear aromatic compound 1 mols which possess the aforementioned K territory and the polynuclear aromatic compound, possesses the aforementioned K territory the polynuclear aromatic compound, or the aforementioned shiroru framework which possess the shiroru framework, in either of the claim 8-14 production method of statement.
[claim16]
16. On the conductive body, gurahuennanoribon of statement is arranged in claim 6 or 7, the layered product.
[claim17]
17. The aforementioned conductive body is gurahuen, in claim 16 the layered product of statement.
  • Applicant
  • ※All designated countries except for US in the data before July 2012
  • NAGOYA UNIVERSITY
  • Inventor
  • ITAMI KENICHIRO
  • ITO HIDETO
  • YANO YUUTA
  • MIYAUCHI YUHEI
  • MITOMA NOBUHIKO
IPC(International Patent Classification)
Specified countries (WO2017131190)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DJ DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KH KN KP KR KW KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
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