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TRIARYLENE COMPOUND AND METHOD FOR PRODUCING SAME commons

Foreign code F170009306
File No. (NU-661)
Posted date Dec 20, 2017
Country WIPO
International application number 2017JP020703
International publication number WO 2017209297
Date of international filing Jun 2, 2017
Date of international publication Dec 7, 2017
Priority data
  • P2016-111353 (Jun 2, 2016) JP
Title TRIARYLENE COMPOUND AND METHOD FOR PRODUCING SAME commons
Abstract A compound represented by general formula (2) [wherein R1 and R2 are as defined above; and X represents a halogen atom] is reacted in the presence of a palladium catalyst and a base. In this manner, it becomes possible to synthesize a triarylene compound under mild conditions using an easily available compound.
Scope of claims [claim1]
1. General system (1):
[In formula, R (1) and R (1 ') the hydrogen atom, substitution or the non substitution aryl basis, or substitution or the non substitution hetero aryl basis are shown.
R (2) shows substitution or the non substitution aryl basis, or substitution or the non substitution hetero aryl basis.
R (3) shows the hydrogen atom.
R'ha substitution or non substitution aromatic hydrocarbon ring or substitution or non substitution complex aromatic ring are shown.
R (1) and R (3) connects, is possible to form ring.
R (1 ') with R (3) connects, is possible to form ring.
R (2) and R'ha it connects, is possible to form ring. ]
So being production method of the polynuclear aromatic compound which is displayed,
In palladium catalyst and under existing of base,
General system (2):
[In formula, R (1) and R (2) is the same to the description above.
X shows the halogen atom. ]
So the reaction process which reacts the chemical compound which is displayed
It has, production method.
[claim2]
2. The description above R (1) the hydrogen atom, substitution or non substitution phenyl group, is substitution or the non substitution naphthyl basis, or substitution or the non substitution benzochieniru basis, in claim 1 production method of statement.
[claim3]
3. The description above R (2) substitution or non substitution phenyl group, is substitution or the non substitution naphthyl basis, or substitution or the non substitution benzochieniru basis, in claim 1 or 2 production method of statement.
[claim4]
4. The description above R' substitution or non substitution benzene ring, is substitution or non substitution naphthalene ring, or substitution or non substitution benzothiophene ring, in either of the claim 1-3 production method of statement.
[claim5]
5. In the aforementioned reaction process, ligand chemical compound is added, in either of the claim 1-4 production method of statement.
[claim6]
6. The aforementioned ligand chemical compound is the phosphine compound, in claim 5 production method of statement.
[claim7]
7. The aforementioned base is alkaline metal carbonate or the alkaline metal fluoride salt, in either of the claim 1-6 production method of statement.
[claim8]
8. In the aforementioned reaction process, carboxylic acid is added, in either of the claim 1-7 production method of statement.
[claim9]
9. After the aforementioned reaction process, the process which causes the cyclization reaction inside the molecule under existing of the oxidizer is had, in either of the claim 1-8 production method of statement.
[claim10]
10. General system (1A1):
[In formula, R (1) and R (1 ') substitution or the non substitution aryl basis, or substitution or the non substitution hetero aryl basis are shown.
R (2) shows substitution or the non substitution aryl basis, or substitution or the non substitution hetero aryl basis.
R'ha substitution or non substitution aromatic hydrocarbon ring or substitution or non substitution complex aromatic ring are shown.
However, R (1), R (1') and R each (2) is non substitution phenyl group, R' 4- (9,12 - diphenyl triphenyl) - 2,5 - dimethyl phenyl group, 4- (2,9,12 - triphenyl triphenyl) - 2,5 - excludes the chemical compound which is the benzene which is substituted with dimethyl phenyl group or triphenyl phenyl group. ]
General system (1A2):
[In formula, R (2) shows substitution or the non substitution aryl basis, or substitution or the non substitution hetero aryl basis.
R'ha substitution aromatic hydrocarbon ring or substitution or non substitution complex aromatic ring are shown.
However, when R (2) is substitution phenyl group and R' is substitution benzene ring, 1,5 - bis [3- (9,9 - dimethyl - 9H-huruoren - 3 - iru) huenirutorihueniren, 7,7' - (1,5 - torihuenirenjiiru) - bisubenzookisazoru, 1,12 - bis ([1,1': 3' and 1 - tar phenyl] - 3 - iru) torihueniren, 3,3' - (1-12-torihuenirenjiiru) bis [9 - phenyl - 9H-karubazoru], 3' - (1-12-torihuenirenjiiru) bis dibenzo thiophene, 1- [3- (buromomechiru) - 5 - methylphenyl] - 12- (3,5 - dimethyl phenyl) - torihueniren, 1- [3- (buromomechiru) - 5 - methylphenyl] - 12 - huenirutorihueniren, 1 - phenyl - 12- (2,4,6 - torimechiruhueniru) - torihueniren, 1- (4 - methylphenyl) - 12 - phenyl - torihueniren, 1- (3,5 - dimethyl phenyl) - 12 - huenirutorihueniren, 1,12 - bis(3,5 - Dimethyl phenyl) - torihueniren, 8,9 - diphenyl dibenzo [f and j] pisen, 2 - iodine - 1,12 - jihuenirutorihueniren, and 1,12 - jihuenirutorihueniren is excluded.
In addition, when R' is non substitution benzene ring, R (2), substitution or non substitution phenyl group, the substitution naphthyl basis and the substitution pirijiru basis, the substitution pillar gill, substitution or the non substitution dibenzofuran basis, substitution or the non substitution dibenzo thiophene basis, substitution or the non substitution carbazole basis, substitution or the non substitution benzo triazole basis, excludes substitution or the non substitution quinoline basis, the torihueniren basis, the phenanthrene basis, the indan dione basis, and the flow connected basis. ]
So the toriariren chemical compound which is displayed.
[claim11]
11. The description above R (1) and R (1 ') the hydrogen atom, substitution or non substitution phenyl group, is substitution or the non substitution naphthyl basis, or substitution or the non substitution benzochieniru basis, in claim 10 the toriariren chemical compound of statement.
[claim12]
12. The description above R (2) substitution or non substitution phenyl group, is substitution or the non substitution naphthyl basis, or substitution or the non substitution benzochieniru basis, in claim 10 or 11 the toriariren chemical compound of statement.
[claim13]
13. The description above R' substitution or non substitution benzene ring, is substitution or non substitution naphthalene ring, or substitution or non substitution benzothiophene ring, in either of the claim 10-12 the toriariren chemical compound of statement.
[claim14]
14. General system (1B):
So it is displayed, the polynuclear aromatic compound.
  • Applicant
  • ※All designated countries except for US in the data before July 2012
  • NAGOYA UNIVERSITY
  • Inventor
  • ITAMI KENICHIRO
  • MURAKAMI KEI
  • KOGA YOSHITO
  • KANEDA TAKESHI
  • SAITO YUTARO
IPC(International Patent Classification)
Specified countries (WO2017209297)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DJ DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JP KE KG KH KN KP KR KW KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
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