TOP > 外国特許検索 > METAL ORGANIC STRUCTURE NANOSHEET AND PRODUCTION METHOD THEREFOR

METAL ORGANIC STRUCTURE NANOSHEET AND PRODUCTION METHOD THEREFOR

外国特許コード F180009407
整理番号 K10509WO
掲載日 2018年4月20日
出願国 世界知的所有権機関(WIPO)
国際出願番号 2017JP026582
国際公開番号 WO 2018016650
国際出願日 平成29年7月21日(2017.7.21)
国際公開日 平成30年1月25日(2018.1.25)
優先権データ
  • 特願2016-144499 (2016.7.22) JP
  • 特願2017-041002 (2017.3.3) JP
発明の名称 (英語) METAL ORGANIC STRUCTURE NANOSHEET AND PRODUCTION METHOD THEREFOR
発明の概要(英語) The present disclosure provides: a method for producing a metal organic structure nanosheet, in which in the case where a bilayer membrane forms a super-swollen lamellar phase in a solvent, a sheet-like metal organic structure is formed between two monolayers constituting a single bilayer membrane. The present disclosure pertains to a metal organic structure nanosheet having a metal organic structure disposed in a sheet-like form between two monolayers constituting a single bilayer membrane, wherein a plurality of the bilayer membranes form a super-swollen lamellar phase in a solvent.
特許請求の範囲(英語) [claim1]
1. 1 Nonbilayer of 2 constituting one of the single molecular layer of the sheet-like between which a metal-organic framework, a plurality of said bilayer lamellor Multiphor Ultrastable defining the phase in a solvent, metal-organic framework nanosheets.
[claim2]
2. Wherein said bilayer, a non-ionic amphipathic substance that, according to claim 1 nanosheets metal-organic framework.
[claim3]
3. A non-ionic amphipathic substance, ester-type surfactant, an ether-type surfactant, fatty acid ester surfactant, alkanolamide-type surfactant, alkylglycoside, higher alcohol is at least one selected from the group consisting of type 1, according to claim 2 nanosheets metal-organic framework.
[claim4]
4. A non-ionic amphipathic substance, and the ether-type surfactant, said surfactant-ether, polyethylene glycol mono alkyl ether selected from the group consisting of polyoxyethylene alkylphenyl ethers and at least one of 1, according to claim 3 nanosheets metal-organic framework.
[claim5]
5.
Wherein said bilayer,(according to the following equation (1) in the formula, n is the number of carbon atoms of the alkyl group represents a block of a hydrophobic, hydrophilic portion is m represents the number of ethylene oxide.) Is composed of a polyethylene glycol mono alkyl ether represented, according to claim 1 nanosheets metal-organic framework.
[claim6]
6. 2<<n/m is 6, according to claim 5 nanosheets metal-organic framework.
[claim7]
7. N is 12 and, when m is 5, according to claim 5 nanosheets metal-organic framework.
[claim8]
8. Wherein the solvent, water or a water-soluble organic solvent comprises a mixture of water and, metal-organic framework according to any one of claims 1-6 nanosheets.
[claim9]
9. N is 12 and, when m is 6, wherein said solvent further comprises water and an organic solvent, the metal-organic framework according to claim 5 nanosheets.
[claim10]
10. Wherein the metal-organic framework, lipophilic ligand in the metal-organic framework constituents, metal-organic framework according to any one of claims 6-9 nanosheets.
[claim11]
11. Swelling the lamellar phase is greater than, the distance between adjacent two of the molecular film having a lamellar structure of 50nm or more, of the metal-organic framework according to any one of claims 1-10 nanosheets.
[claim12]
12. In a dispersed state in the liquid metal-organic framework comprises nano-sheets, the metal-organic framework is nano-sheets, metal-organic framework according to any one of claims 1-11 is nano-sheets, metal-organic framework nanosheet dispersion.
[claim13]
13. Nonbilayer solvent swelling a lamellar phase and in the case of an ultra, 1 nonbilayer of constituting one of the single molecular layer of 2 nano-sheet is formed, the manufacturing method of the nano-sheets.
[claim14]
14. Nano-sheets is composed of a metal-organic framework, a method of manufacturing according to claim 13 nano-sheets.
[claim15]
15. A second formation of the molecular film in a solvent, wherein the organic ligand in a solvent is added, to form a lamellar phase Multiphor nonbilayer superantigens and, thereafter, the metal ions are added to a solvent, 2 to 1 nonbilayer of one of the single molecular layer between the nano-metal-organic framework to form the sheet, the method of manufacturing according to claim 14 nano-sheets.
[claim16]
16. 1 The method of claim 2 nonbilayer constituting one monolayer of the metal-organic framework between the nano-sheet after the forming, removing said bilayer, a method of manufacturing according to claim 14 or 15 nano-sheets.
[claim17]
17.
Wherein said bilayer,(according to the following equation (1) in the formula, n is the number of the alkyl group represents a block of a hydrophobic, hydrophilic m represents the number of ethylene oxide unit.) Is composed of a polyethylene glycol mono alkyl ether represented, the manufacturing method of any one of claims 14-16 sheet and a combination thereof.
[claim18]
18. 2<<n/m is 6, the method of manufacturing according to claim 17 nano-sheets.
[claim19]
19. N is 12 and, when m is 5, the method of manufacturing according to claim 17 nano-sheets.
[claim20]
20. Wherein the solvent is water or a water soluble organic solvent comprises a mixed solution of, the manufacturing method of any one of claims 15-19 nanosheets.
[claim21]
21. N is 12 and, when m is 6, and further wherein said solvent comprises water and an organic solvent, a method of manufacturing according to claim 17 nano-sheets.
[claim22]
22. Wherein the metal-organic framework, lipophilic ligand in the metal-organic framework and the components, a method for producing any one of claims 14-21 and a combination thereof.
[claim23]
23. Nano-sheets are composed of metal or metal oxide, a method of manufacturing according to claim 13 nano-sheets.
[claim24]
24. Forming nonbilayer solvent, said solvent amphiphilic substance is added, nonbilayer superantigens swelling formed a lamellar phase and, then, an oxygen atom in said solvent having an oxygen atom or a metal-containing compound does not added to the metal-containing compound, 2 to 1 nonbilayer wherein one monolayer of the metal nanoparticles or metal oxide nanoparticles that between the sheet to form the sheet, the method of manufacturing according to claim 23 nano-sheets.
[claim25]
25. Wherein the solvent is, containing a mixture of water and an organic solvent, a method of manufacturing according to claim 24 nano-sheets.
[claim26]
26. Further, in the solvent for the active additives, a method of manufacturing according to claim 24 or 25 nano-sheets.
[claim27]
27. The amphiphilic substance, in which the anionic amphiphile, a method for producing any one of claims 24-26 and a combination thereof.
[claim28]
28. The nano-metal-organic framework according to any one of claims 1-11 sheet, in the gas separation membrane.
[claim29]
29. The carbon dioxide separation device for separating or nitrogen, the gas separation membrane according to claim 28.
[claim30]
30. 1 Nonbilayer of 2 constituting one of the single molecular layer of the sheet arranged in the form of a metal oxide, in a solvent in which a plurality of said bilayer form a lamellar phase and are ultra-swelling, sheet metal oxide nanoparticles.
[claim31]
31. 1 Nonbilayer of 2 constituting one of the single molecular layer of the sheet-like between a gold compound, a plurality of said bilayer ultra-swelling solvent form a lamellar phase, the gold-nano-sheet.
  • 出願人(英語)
  • ※2012年7月以前掲載分については米国以外のすべての指定国
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • 発明者(英語)
  • UCHIDA YOSHIAKI
  • NISHIYAMA NORIKAZU
  • OMIYA TAKERU
  • NAKAI TAKUTO
国際特許分類(IPC)
指定国 (WO201816650)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DJ DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JO JP KE KG KH KN KP KR KW KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
参考情報 (研究プロジェクト等) PRESTO Molecular technology and creation of new functions AREA
ライセンスをご希望の方、特許の内容に興味を持たれた方は、問合せボタンを押してください。

PAGE TOP

close
close
close
close
close
close