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NOVEL DIELECTRIC MATERIAL NEW 新技術説明会

外国特許コード F180009433
整理番号 (AF39P003)
掲載日 2018年7月23日
出願国 世界知的所有権機関(WIPO)
国際出願番号 2017JP033629
国際公開番号 WO 2018056237
国際出願日 平成29年9月19日(2017.9.19)
国際公開日 平成30年3月29日(2018.3.29)
優先権データ
  • 特願2016-182562 (2016.9.20) JP
発明の名称 (英語) NOVEL DIELECTRIC MATERIAL NEW 新技術説明会
発明の概要(英語) Provided are a new dielectric material and an electrostrictive material. The dielectric material or electrostrictive material comprises a charge separated-type non-coulombic ionic solid in which complex cations comprising metal elements and ligands are integrated forming cation clusters, the cation clusters being arranged in a closest packing structure with vacancies in which anions are integrated, forming anion clusters.
特許請求の範囲(英語) [claim1]
1. A complex of ligand and the metal element in the form of the accumulation form cation cluster cations, the cation cluster is arranged in a close-packed structure, the anion vacancies formed in the form of the accumulation charges non-separation type containing ionic solids governing Coulomb force in the dielectric material.
[claim2]
2. Wherein the charge separation type ionic solid non-coulomb force governing, 2 2 and the two types of metal elements consisting of a type of ligand complex cation is a cation cluster and integrated in the multi-form, arranged in the form of the cation cluster having a face centered cubic, the holes of the tetrahedron is a counter anion of the inorganic anion is integrated with the electric charge separation is formed non-type-ion-dominated Coulomb force according to claim 1 solid dielectric material.
[claim3]
3. Wherein the cation cluster, Group 11 and Group 10 elements selected from (M1) and, 6 group, 9 group and 13 group element selected from the group (M2) are 2 type of ligand (X1and X2) coupled via M1M2dissloving-ten core complex cation cluster claims 1 or 2 in volume of said dielectric material.
[claim4]
4. Wherein the charge separation type ionic solid non-coulomb force governing, represented by the general formula (1) (M1)l(M2)m(X1)n(X2)o(X3)p, qH2O, (1) (formulae, M1is, 10 group and 11 is selected from Group an element; M2is, 6 group, 9 group and 13 is selected from Group an element; X1is, at least 2 two phosphino groups ligand to; X2is, at least 1 two thiol group and a carboxyl group in the ligand having; X3is, anion; l and m are, in each of the number of 2-6, the total number becomes 6-10; n is the number of 1-2; o is the number of 2-6; p and q are, respectively indicative of the number of 1-16.) Of the type to the charge separation represented by the non-ionic solid governing a coulomb force is any one of claims 1-3 volume of said dielectric material.
[claim5]
5. X1is, at least one diarylphosphino 2 having any one of claims 1-4 ligand of said dielectric material.
[claim6]
6. X2is, thiol group and a carboxyl group other than a hydrogen-bonding functionality to the ligand having any one of claims 1-5 in volume of said dielectric material.
[claim7]
7. Wherein the charge separation type governing the ionic solid non-Coulomb force, the electric resistance value changes in the temperature of the 100K 450K from the any one of claims 1-6 drops below 1/100000 in volume of said dielectric material.
[claim8]
8. A dielectric material of any one of claims 1-7 thermometer.
[claim9]
9. A dielectric material of any one of claims 1-7 thermistor.
[claim10]
10. Any one of claims 1-7 volume of said dielectric material is used as a thermostat, the protection circuit device operating at a temperature rise.
[claim11]
11. A complex of ligand and the metal element in the form of the accumulation form cation cluster cations, the cation cluster is arranged in a close-packed structure, the anion vacancies formed in the form of the accumulation charges non-separation type containing ionic solids governing a coulomb force is an electrostrictive material.
[claim12]
12. Wherein the charge separation type ionic solid non-coulomb force governing, 2 2 and the two types of metal elements consisting of a type of ligand polynuclear complex cation cluster is formed integrated with the cation, the cation cluster having a face centered cubic arrangement, the holes of the tetrahedron is a counter anion of the inorganic anion is integrated and formed on the electric charge separation are governed by a coulomb force type of non-ionic type according to claim 11 an electrostrictive material of the solid.
[claim13]
13. Wherein the cation cluster, Group 11 and Group 10 elements selected from (M1) and, 6 group, 9 group and 13 group element selected from the group (M2) are 2 type of ligand (X1and X2) coupled via M1M2dissloving-tens of claims 11 or 12 cation cluster core complex is an electrostrictive material.
[claim14]
14. Wherein the charge separation type ionic solid non-coulomb force governing, represented by the general formula (1) (M1)l(M2)m(X1)n(X2)o(X3)p, qH2O, (1) (formulae, M1is, 10 group and 11 is selected from Group an element; M2is, 6 group, 9 group and 13 is selected from Group an element; X1is, at least 2 two phosphino groups ligand to; X2is, at least 1 two thiol group and a carboxyl group in the ligand having; X3is, anion; l and m are, in each of the number of 2-6, the total number becomes 6-10; n is the number of 1-2; o is the number of 2-6; p and q are, respectively indicative of the number of 1-16.) To the charge separation represented by the charge separation governing a coulomb force of the non-ionic type comprises an electrostrictive material of any one of claims 11-13 solid.
[claim15]
15. X1is, diarylphosphino 2 having at least one of any one of claims 11-14 nickelcomplex of electrostrictive material.
[claim16]
16. X2is, thiol group and a carboxyl group other than hydrogen bonding functionality of any one of claims 11-15 ligand having an electrostrictive material.
[claim17]
17. Wherein the charge separation type governing the ionic solid non-coulomb force, by means of voltage application to any one of claims 11-16 in isotropic shrinkage of electrostrictive material.
[claim18]
18. Said actuator having an electrostrictive material of any one of claims 11-17.
[claim19]
19. (1a) In the formula (M1)l(M2)m(X1)n(X2a)o, (X3)p, qH2O, (1a) (formulae, M1is, 10 group and 11 is selected from Group an element; M2is, 6 group, 9 group and 13 is selected from Group an element; X1is, at least 2 two phosphino groups ligand to; X2ais, at least 1 two thiol group and a carboxyl group ligand having a (penicillamine tEM): X3is, anion; l and m are, in each of the number of 2-6, the total number becomes 6-10; n is the number of 1-2; o is the number of 3-6; p and q are, respectively indicative of the number of 1-16.) Represented by the polynuclear metal complex.
[claim20]
20. X1is, at least one of 2 diarylphosphino group according to claim 19 polynuclear metal complex ligand.
[claim21]
21. X2ais, in addition to the thiol group and a carboxyl group, a hydrogen-bondable functional group is a ligand having a metal complex multinuclene of claims 19 or 20.
  • 出願人(英語)
  • ※2012年7月以前掲載分については米国以外のすべての指定国
  • JAPAN SCIENCE AND TECHNOLOGY AGENCY
  • 発明者(英語)
  • KONNO TAKUMI
  • YAMASHITA SATOSHI
国際特許分類(IPC)
指定国 (WO201856237)
National States: AE AG AL AM AO AT AU AZ BA BB BG BH BN BR BW BY BZ CA CH CL CN CO CR CU CZ DE DJ DK DM DO DZ EC EE EG ES FI GB GD GE GH GM GT HN HR HU ID IL IN IR IS JO JP KE KG KH KN KP KR KW KZ LA LC LK LR LS LU LY MA MD ME MG MK MN MW MX MY MZ NA NG NI NO NZ OM PA PE PG PH PL PT QA RO RS RU RW SA SC SD SE SG SK SL SM ST SV SY TH TJ TM TN TR TT TZ UA UG US UZ VC VN ZA ZM ZW
ARIPO: BW GH GM KE LR LS MW MZ NA RW SD SL SZ TZ UG ZM ZW
EAPO: AM AZ BY KG KZ RU TJ TM
EPO: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
OAPI: BF BJ CF CG CI CM GA GN GQ GW KM ML MR NE SN ST TD TG
参考情報 (研究プロジェクト等) CREST Establishment of molecular technology towards the Creation of New Functions AREA
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