Top > Search Research paper > (In Japanese)単一分子・原子レベルの反応制御 ヘテロ原子間結合活性化による新物質・新反応の開拓

(In Japanese)単一分子・原子レベルの反応制御 ヘテロ原子間結合活性化による新物質・新反応の開拓

Research report code R990004265
Posted date Feb 6, 2001
  • (In Japanese)田中 正人
  • (In Japanese)経済産業省 産業技術総合研究所(旧物質工学工業技術研究所)
Research organization
  • (In Japanese)経済産業省 産業技術総合研究所(旧物質工学工業技術研究所)
Report name (In Japanese)単一分子・原子レベルの反応制御 ヘテロ原子間結合活性化による新物質・新反応の開拓
Technology summary (In Japanese)本研究の目的は,機能材料や機能物質としての有用性が認識されていながら,分子レベルでの金属錯体との反応性の研究が比較的少ないヘテロ原子(周期律表13族から17族に属する原子)を含む物質群について,結合開裂・生成挙動を検討し,それを応用して新規な触媒的合成反応,生理活性物質,重合反応,高分子化合物などを開拓することである。主な研究項目と成果を次に示した。
Research field
  • Catalytic reactions (heterogeneous system)
  • Organosilicon compounds
  • Polymerization in general
  • Electronic structure of molecules
Published papers related (In Japanese)(1)Chem. Lett., 1998, 431. Ruthenium-catalyzed regioselective addition of phosphinic acids with alkynes forming alkenyl phosphinates. Rui-mao Hua, M. Tanaka
(2)Organometallics, 17, 2926 (1998). Synthesis of Carbodiimidotitanium Complexes by the Reaction of (Trimethylstannyl)carbodiimides with Titanium Chlorides. G. Veneziani, S. Shimada, M. Tanaka.
(3)J. Organomet. Chem., 564, 81 (1998). Synthesis of partially network polyphenylgermanes by dehydrogenative coupling of phenylgermane. N. Choi, M. Tanaka.
(4)Chem. Lett., 1998, 763. Synthesis of highly thermally heat-resistant soluble polymers through hydrosilylation polymerization between octakis(hydrosilsesquioxane) and diynes. T.-a. Kobayashi, T. Hayashi, M. Tanaka.
(5)J. Am. Chem. Soc., 120, 8249 (1998). The first platinum(0)-catalyzed regio- and stereoselective thiosilylation of alkynes using disulfides and disilanes: A new strategy for in- roducing two different hetero-atoms into carbon-carbon unsaturated bonds. L.-B. Han, M. Tanaka.
(6)Tetrahedron Lett., 39, 9043 (1998). Regio- and stereoselective 1,4-borylstannation of 1,3-dienes promoted by palladium catalysts. S-y. Onozawa, Y. Hatanaka, M. Tanaka.
(7)J. Am. Chem. Soc., 120, 12365(1998). The first example of rhodium(I)-catalyzed regio- and stereoselective chloroesterification of alkyneswith chloroforate Esters. R. Hua, S. Shimada, M. Tanaka.
(8)Chem. Lett., 1999, 159. Synthesis and spectral properties of novel Si-Ru-Ru-Si-C6H4 polymers. P. Nombel, Y. Hatanaka, S. Shimada, M. Tanaka.
(9)Chem. Commun., 1999, 395. Transition metal-catalysed addition reactions of H-heteroatom and inter-heteroatom bonds to carbon-carbon unsaturated linkages via oxidative additions. L.-B. Han, M. Tanaka.
(10)Organometallics, 18, 291, (1999). Reaction of 1,2-disilylbenzene with bis[1,2-bis(di-methylphosphino)ethane]nickel(0). Isolation and characterization of the first silylnickel(IV) complex. S. Shimada, M.L.N. Rao, M. Tanaka.
Research project
  • Core Research for Evolutional Science and Technology;Single Molecule and Atom Level Reactions
Information research report
  • (In Japanese)田中 正人. 単一分子・原子レベルの反応制御 ヘテロ原子間結合活性化による新物質・新反応の開拓. 戦略的基礎研究推進事業 平成10年度 研究年報,1999. p.350 - 352.