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(In Japanese)生体分子解析用金属錯体プローブの開発

Research report code R990004272
Posted date Feb 6, 2001
  • (In Japanese)松本 和子
  • (In Japanese)早稲田大学理工学部
Research organization
  • (In Japanese)早稲田大学理工学部
Report name (In Japanese)生体分子解析用金属錯体プローブの開発
Technology summary (In Japanese)金属錯体は中心金属の種類と酸化状態,および配位子の構造と電子的性質により,多様な物理的,化学的性質を示す。本研究では,特殊な配位子や異常酸化状態の金属を含む金属錯体を合成し,金属-配位子,又は金属-金属間の協同的相互作用を発現させることにより,
Research field
  • Analytical instruments
  • Platinum family element complexes
  • Biochemical analytical methods
  • Biosubstance in general
  • Molecular structure
Published papers related (In Japanese)(1)J. Yuan, K. Matsumoto, and H. Kimura A New Tetradentate β -Diketonate-Europium Chelate That Can Be Covalently Bound to Proteins for Time-Resolved Fluoroimmunoassay Anal. Chem., 70, 596-601, (1998).
(2)J. Yuan, G. Wang, H. Kimura, and K. Matsumoto, Sensitive Time-Resolved Fluoroimmunoassay of Human Thyroid-Stimulating Hormone by Using a New Europium Fluorescent Chelate as a Label Anal. Sci., 14, 421-423, (1998).
(3)K. Matsumoto, Y. Nagai, J. Matsunami, K. Mizuno, T. Abe, R. Somazawa, J. Kinoshita, and H. Shimura A Synthetic Route to Alkyl-Pt(III) Dinuclear Complexes from Olefins and Its Implication on the Olefin Oxidation Catalyzed by Amidate-Bridged Pt(III) Dinuclear Complexes J. Am. Chem. Soc., 120, 2900-2907, (1998).
(4)K. Matsumoto, Y. Noguchi, and N. Yoshida Synthesis and Antitumor activity of Platinum(II) Complexes of Amino-Cyclodexitrin Inorg. Chim. Acta, 272, 162-167, (1998).
(5)I. Miyashita, K. Matsumoto, M. Kobayashi, A. Nagasawa and J. Nakayama Synthesis and Crystal Structure of a Dinuclear Platinum (II) bis(N, N-diethylamino) carbeniumdithio-carboxylate Complex Pt2{m-(Et2N)2C2S2}2Cl4 ・0.5CH2Cl2: Structural Study of the Coordinated Inner Salt Inorg. Chim. Acta, 283, 256-259 (1998).
(6)T. Furuhashi, M. Kawano, Y. Koide, R. Somazawa, and K. Matsumoto Structural Studies of the Hydrazine and Ammine Complexes of the Dinuclear Ruthenium Polysulfide Complexes Inorg. Chem., 38, 109-114, (1999).
(7)H. Kimura, J. Yuan, G. Wang, K. Matsumoto, and M. Mukaida Highly Sensitive Quantitation of methamphetamine by Time-Resolved Fluoroimmunoassay Using a New Europium Chelate as a Label J. Anal. Toxicol., 23, 11-16 (1999).
(8)K. Yoshikawa, J. Yuan, K. Matsumoto, and H. Kimura Time-Resolved Fluorometric Detection of DNA Using a Tetradentate β-Diketonate Europium Chelate as a Label Anal. Sci., 15, 121-124 (1999).
(9)J. Yuan, G. Wang, H. Kimura, and K. Matsumoto Highly Sensitive Detection of Bensulfuron-methyl by Time-Resolved Fluoroimmunoassay Using a Tetradentate b-Diketonate Europium Chelate as a Label Anal. Sci., 15, 125-128 (1999).
Research project
  • Core Research for Evolutional Science and Technology;Single Molecule and Atom Level Reactions
Information research report
  • (In Japanese)松本 和子. 単一分子・原子レベルの反応制御 生体分子解析用金属錯体プローブの開発. 戦略的基礎研究推進事業 平成10年度 研究年報,1999. p.381 - 388.